The decomposition of t-butyl erythro- and threo-2,3-diphenylperoxybutyrate in solution. The product analysis and the cage effect.
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概要
- 論文の詳細を見る
Decomposition of <I>t</I>-butyl <I>erythro</I>- and <I>threo</I>-2,3-diphenylperoxybutyrate was examined in solution at 60 °C; there was no indication of induced decomposition taking place as is the case with <I>t</I>-butyl 2,3-diphenylperoxypropionate. Various hydrocarbons resulting from the reaction of the 1,2-diphenylpropyl radical in a variety of ways were identified in the product, and <I>t</I>-butyl 1,2-diphenylpropyl ether was found to be formed as cage recombination product in the <I>threo/erythro</I> isomeric ratio which depended on the stereochemistry of the starting peroxybutyrate.
- 公益社団法人 日本化学会の論文
著者
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Yoshida Masayuki
Department Of Applied Genetics Medical Research Institute Tokyo Medical And Dental University
-
Simamura Osamu
Department of Chemistry Faculty of Science The University of Tokyo
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Ochiai Tameichi
Department of Chemistry, Faculty of Science, Tokyo University
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