Mechanism for light induced hydrogen isotope exchange in benzonitrile.
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概要
- 論文の詳細を見る
Light induced tritiation of benzonitrile with diethylamine[N<SUP>3</SUP>H] or triethylamine-tritiated water was studied with respect to quenching of benzonitrile fluorescence by the amines and the tritium distribution in the nucleus. A mechanism involving an exciplex possessing charge transfer nature was proposed.
著者
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Sakuragi Hirochika
Department Of Chemistry University Of Tsukuba
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Tokumaru Katsumi
Institute Of Chemistry University Of Tsukuba
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Kaneko Hiroyuki
Department Of Animal Production Kyushu National Agricultural Experiment Station
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Morikawa Naotake
Radioisotope Center The University Of Tokyo
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Yoshida Masayuki
Department Of Applied Genetics Medical Research Institute Tokyo Medical And Dental University
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Kitamura Akihide
Institute of Chemistry, The University of Tsukuba
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Oohashi Kunio
Radioisotope Centre, The University of Tokyo
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Ito Tomiyasu
Department of Chemistry, Faculty of Science, The University of Tokyo
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