Dye-Sensitized Oxygenation and Dimerization of 4-Methoxystyrene through Electron Transfer.
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概要
- 論文の詳細を見る
Photoreactions of 4-methoxystyrene (<B>1</B>) sensitized with dyes such as Acriflavine, Rhodamine 6G, and Methylene Blue in methanol under oxygen afforded 4-methoxybenzaldehyde, its dimethyl acetal, and 2-methoxy-2-(4-methoxyphenyl)ethanol as oxidation products together with the corresponding dimers, <I>cis</I>- and <I>trans</I>-cyclobutanes in a ratio of cis/trans ca. 5/95. On the basis of quenching studies of fluorescence and T–T absorption of the dyes, the oxygenation and dimerization are proposed to proceed through an electron transfer from <B>1</B> to excited singlet dyes but not to involve generation of singlet oxygen.
- 公益社団法人 日本化学会の論文
著者
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SAKURAGI Hirochika
Department of Chemistry, University of Tsukuba
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Sakuragi Hirochika
Department Of Chemistry University Of Tsukuba
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Kojima Masanobu
Faculty Of Liberal Arts Shinshu University
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Kuriyama Yasunao
Department Of Chemistry School Of Science Kitasato University
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Tokumaru Katsumi
Department of Chemistry Faculty of Science The University of Tokyo
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