Unambiguous proof of nitrile formation from pyrazine skeleton through photo-oxidative degradation. Isolation and structural determination of photodegraded product of amorphous poly(2,5-distyrylpyrazine).
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概要
- 論文の詳細を見る
In the presence of oxygen, amorphous poly(2,5-distyrylpyrazine) film was readily photodegraded, accompanied by cleavage of the pyrazine rings in the main chain. From the photodegraded film, <I>t</I>-2,<I>c</I>-4-diphenylcyclobutane-<I>r</I>-1,<I>t</I>-3-dicarbonitrile was isolated in 13% yield.
- 公益社団法人 日本化学会の論文
著者
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HASHIMOTO Yukihiko
Department of Synthetic Chemistry, Faculty of Engineering, The University of Tokyo
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Hashimoto Yukihiko
Department Of Chemistry And Biotechnology Faculty Of Engineering The University Of Tokyo
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Sakuragi Hirochika
Department Of Chemistry University Of Tsukuba
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Hasegawa Masaki
Department Of Materials Science And Technology Faculty Of Engineering Toin University Of Yokohama
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Tokumaru Katsumi
Department of Chemistry Faculty of Science The University of Tokyo
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Adegawa Yutaka
Department of Synthetic Chemistry, Faculty of Engineering, The University of Tokyo
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Onodera Kazuyuki
Department of Chemistry, University of Tsukuba
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