Behavior of the excited cis singlet state of a one-way isomerizing olefin. Further insight into potential energy surfaces of 1-(3,3-dimethyl-1-butenyl)pyrene.
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概要
- 論文の詳細を見る
The decay processes of the excited singlet state and potential energy surfaces of 1-(3,3-dimethyl-1-butenyl)pyrene (BP) were investigated. A long-lived fluorescence from the cis isomer and involvement of a quantum chain process for one-way isomerization suggest that the isomerization on direct excitation proceeds in the triplet manifold after intersystem crossing at the cis conformation.
- 公益社団法人 日本化学会の論文
著者
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KAWANISHI Yuji
Research Institute for Polymers and Textiles
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Arai Tatsuo
Department Of Applied Physics Nagoya University
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Sakuragi Hirochika
Department Of Chemistry University Of Tsukuba
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Tokumaru Katsumi
Department of Chemistry Faculty of Science The University of Tokyo
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Okamoto Hiroaki
Department of Advanced Materials and Science, Faculty of Engineering, Yamaguchi University
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