Important role of fluorescence reabsorption mechanism in sensitized reaction of unsaturated lactones. Evidence against "the orbital symmetry correlations in sensitization".
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概要
- 論文の詳細を見る
Evidence are presented against Ullman's "the orbital symmetry correlations" between excited aromatic hydrocarbon sensitizers and 4-benzylidene-2-phenyl-5-oxazolone. It is now shown that the oxazolone efficiently quenches the triplet sensitizers regardless of Ullman's classification, and the fluorescence emitted from the sensitizers is reabsorbed by the oxazolone and its wavelength seems to govern the reported reaction course.
- 公益社団法人 日本化学会の論文
著者
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Sakuragi Hirochika
Department Of Chemistry University Of Tsukuba
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Ono Isao
Department Of Chemistry College Of Science And Engineering Aoyama Gakuin University
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Tokumaru Katsumi
Department of Chemistry Faculty of Science The University of Tokyo
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Sakuragi Hirochika
Department of Chemistry, Faculty of Science, The University of Tokyo
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Hata Norisuke
Deparment of Chemistry, College of Science and Engineering, Aoyama Gakuin University
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