Backbone rearrangements of 3.ALPHA.,4.ALPHA.-epoxyshionane into bacchar-12-en-3.ALPHA.-ol and D. B-friedo-bacchar-5(10)en-3.ALPHA.-ol.
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概要
- 論文の詳細を見る
Upon treatment with boron trifluoride etherate, 3α,4α-epoxyshionane (<B>7</B>) rearranged into bacchar-12-en-3α-ol (<B>9</B>) and D : B-friedo-bacchar-5(10)-en-3α-ol (<B>10</B>), and their structures have been determined. Revision of the structure for the latter product from previously reported D : C-friedo-bacchar-8-en-3α-ol (<B>20</B>) to <B>10</B> was described.
- 公益社団法人 日本化学会の論文
著者
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Tachibana Kazuo
Department Of Chemistry School Of Science The University Of Tokyo
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Takahashi Takeyoshi
Department Of Applied Biological Science College Of Agriculture And Veterinary Medicine Nihon Univer
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Yamada Sachiko
Department Of Biomolecular Science Faculty Of Science University Of Toho
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Tsuyuki Takahiko
Department Of Chemistry College Of General Education University Of Tokyo
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Yamada Shuzo
Department Of Chemistry University Of Electro-communications
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Tanahashi Yoshiaki
Department of Chemistry, Faculty of Science, The University of Tokyo
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Moriyama Yoshihiko
Department of Chemistry, Faculty of Science, The University of Tokyo
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Tachibana Kazuo
Department of Chemistry, Faculty of Science, The University of Tokyo
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