Effect of Gas Composition on TiN Thin-Film Fabrication in N_2/H_2/Ar/TiCl_4 Inductively Coupled Plasma-Enhanced Chemical Vapor Deposition System : Semiconductors
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概要
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TiN films were deposited in a N_2/H_2/Ar/TiCl_4 rf inductively coupled plasma and the effect of gas composition on the properties of the TiN films were analyzed through investigation of the plasmas with a Langmuir single probe and a mass spectrometer. The quality of TiN films depended critically on the concentration of H and N radicals. H_2 had the effect of removing Cl from the TiCl_4 and reducing N radicals in the plasma although the plasma density and electron temperature were not significantly affected. Accordingly, high-quality TiN films with low Cl content and good electric properties were obtained with 10 - 20% of H_2. With the addition of Ar, the plasma density increased and the dissociation of the precursors was enhanced; as a result, the production of N and H radicals was enhanced and the quality of TiN films was improved.
- 社団法人応用物理学会の論文
- 2001-08-15
著者
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Jang Seong-soo
Department Of Materials Science And Engineering Korean Advanced Institute Of Science And Technology
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Lee Won-jong
Department Of Computer Science Yonsei University
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Lee Won-jong
Department Of Materials Science And Engineering Korean Advanced Institute Of Science And Technology
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