Complexation and Fluorescence Behavior of Tris[(1-naphthoyloxy)ethyl]amine

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概要

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• Tris[(1-naphthoyloxy)ethyl]amine (1) was found to display unique photophysical properties in the presence of the guest cations. The amine (1) revealed a broad emission band around 440nm that is typical of a structureless emission of a naphthoyl excimer and a naphthalene-amine exciplex. From the result of X-ray analysis, the amine (1) adopt a tripod conformation with crystallographic C_3 symmetry. Complexation of 1 with Al^<3+> increased the emission intensity of a factor by 5.3 in H_2O-CH_3OH (1:1 v/v).

• 九州大学の論文

著者

• 加藤 修雄

  大阪大学産業科学研究所

• YAMAMOTO Emi

  Graduate School of Engineering Sciences, 39, Kyushu University

• SAKURAI Tadamitsu

  Department of Applied Chemistry, Faculty of Engineering, Kanagawa University

• Kato Nobuo

  Department Of Bacteriology Nagoya University School Of Medicine

• Mori Atsunori

  Department Of Synthetic Chemistry The University Of Tokyo

• Sakurai Takeshi

  Ishikawajima-harima Heavy Industries Co. Ltd.

• Yamamoto Emi

  Graduate School Of Engineering Science 39 Kyushu University

• Kato N

  Osaka Univ. Ibaraki Jpn

• Kato N

  Department Of Bacteriology Nagoya University School Of Medicine

• Sakurai Tadamitsu

  Department Of Applied Chemistry Faculty Of Engineering Kanagawa University

• Sakurai Tadamitsu

  Department Or Applied Chemistry Faculty Of Engineering Kanagawa University

• 加藤 修雄

  阪大産研

• Samejima T

  Department Of Chemistry College Of Science And Engineering Aoyamagakuin University

• Kubo K

  Kyushu Univ.

• Mori A

  Department Of Synthetic Chemistry The University Of Tokyo

• Kubo K

  Kyushu Univ. Kasuga

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