1D09 5-アルコキシ-2-(4-アルコキシベンゾイルアミノ)トロポンの液晶性発現とCH-π相互作用
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概要
- 論文の詳細を見る
The X-ray crystallographic structural analysis of 5-butoxy-2-(4-methoxybenzoylamino)tropone, a smectic C type liquid crystalline compound with non-sigmatropic troponoid core, revealed a CH-π interaction between the benzoyl π-system and the β-hydrogen of the 5-butoxy group on the tropone ring. Noteworthy is that 5-methoxy-2-(4-alkoxybenzoylamino)tropone, lacking the β-hydrogen, was non-mesogenic while 5-alkoxy-2-(4-methoxybenzoylamino)tropone was mesogenic. Some substituent effects of the benzoyl group were also discussed.
- 日本液晶学会の論文
- 1995-09-10
著者
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加藤 修雄
大阪大学産業科学研究所
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森 章
九大総理工
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竹下 齋
九大総理工・九大機能研
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Kato N
Osaka Univ. Ibaraki Jpn
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Kato N
Department Of Bacteriology Nagoya University School Of Medicine
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Mori A
Department Of Synthetic Chemistry The University Of Tokyo
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平山 健
九大総理工・九大機能研
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加藤 修雄
九大総理工・九大機能研
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