Condensation of Polyfluoroalkanols to Tropolone to Form 2-(Polyfluoroalkoxy) tropones and Their High-Pressure Diels-Alder Reaction with [60] Fullerene
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概要
- 論文の詳細を見る
The Mitsunobu reaction of tropolone with 2-(perfluoroalkyl) ethanols, low-reactive nucleophiles, afforded 2-(polyfluoroalkoxy) tropones in good yields. The high-pressure (300MPa) Diels-Alder reaction of several 2-(polyfluoroalkoxy) tropones with C_<60> gave the [4+2] cycloadducts. Modification of the fullerene with polyfluoroalkoxylated homobarrelenone framework resulted in the great enhancement of solubility in common organic solvents.
- 九州大学の論文
- 1995-11-15
著者
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加藤 修雄
大阪大学産業科学研究所
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Takeshita H
Kyushu Univ.
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Takeshita Hitoshi
Tohwa University
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Takeshita Hitoshi
Tohwa Institute For Orient Studies Tohwa University
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Kato N
Osaka Univ. Ibaraki Jpn
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Kato N
Department Of Bacteriology Nagoya University School Of Medicine
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Ikeda Yukari
Institute Of Advanced Material Study 86 Kyushu University
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Mori A
Department Of Synthetic Chemistry The University Of Tokyo
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