Synthetic Photochemistry. LXX. Efficient Formation of An Eudesmane Skeleton by the de Mayo Reaction between 1-Isopropyl-4-methylcyclohexa-1,3-diene and Methyl 2,4-Dioxopentanoate

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概要

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• The de Mayo reaction of methyl 2,4-dioxopentanoate and 1-isopropyl-4-methylcyclohexa-1,3-diene afforded, together with an oxetane and a [4+2] adduct, a dihydropyran derivative, which gave an eudesmane derivative by acid treatment. The dihydropyran and the [4+2] adduct were formed from the common intermediate.

• 九州大学の論文
• 1996-11-12

著者

• Takeshita H

  Kyushu Univ.

• Takeshita Hitoshi

  Tohwa University

• Takeshita Hitoshi

  Tohwa Institute For Orient Studies Tohwa University

• Mori A

  Institute Of Advanced Material Study 86 Kyushu University

• HIRATA Narukuni

  Interdisciplinary Graduate School of Engineering Sciences, Kyushu University

• Hirata N

  Kyushu Univ.

• Hirata Narukuni

  Interdisciplinary Graduate School Of Engineering Sciences Kyushu University

• Hatsui T

  Kyushu Univ. Fukuoka Jpn

• Mori A

  Komatsu Ltd. Kanagawa Jpn

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