Addition Reaction of 2-Pyrone-5-carboxylate with α-Terpinene. An Attempted Conversion of Monoterpene to Sesquiterpenoids

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概要

• 論文の詳細を見る

• Methyl 2-pyrone-5-carboxylate reacted with α-terpinene site- and regio-selectively to give tricycle lactones at 110℃. At a higher temperature, decarboxylation and subsequent intramolecular cycloaddition took place to afford a triene and a tetracyclic ester. A triene diester and hydroxy diesters were synthesized from the lactones. Attempted conversion of them to eudesmanoids are described.

• 九州大学の論文
• 1996-11-12

著者

• Takeshita H

  Kyushu Univ.

• Takeshita Hitoshi

  Tohwa University

• Takeshita Hitoshi

  Tohwa Institute For Orient Studies Tohwa University

• HIRATA Narukuni

  Interdisciplinary Graduate School of Engineering Sciences, Kyushu University

• Hirata N

  Kyushu Univ.

• Hirata Narukuni

  Interdisciplinary Graduate School Of Engineering Sciences Kyushu University

• Hatsui T

  Kyushu Univ. Fukuoka Jpn

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