Synthetic Photochemistry. LIX. Intramolecular Photocycloaddition of 2-(3-Butenyl)-2, 6-dimethyl-4H-1, 3-dioxin-4-one
スポンサーリンク
概要
- 論文の詳細を見る
2-(3-Butenyl)-2, 6-dimethyl-4H-1, 3-dioxin-4-one, an adduct of diketene to 1-hexen-5-one, formed a single photocycloadduct with opposite regioselectivity against the ordinary manner. This could be explained in terms of a non-bonding interaction between two endo-hydrogens of the cage-shaped photocyclisates.
- 九州大学の論文
- 1992-11-30
著者
-
加藤 修雄
大阪大学産業科学研究所
-
Takeshita H
Kyushu Univ.
-
Takeshita Hitoshi
Tohwa University
-
Takeshita Hitoshi
Tohwa Institute For Orient Studies Tohwa University
-
NAGANO Yoshiaki
Towa Institute of Technology
-
Kato N
Osaka Univ. Ibaraki Jpn
-
Mori A
Department Of Synthetic Chemistry The University Of Tokyo
関連論文
- 46.フシコクシン生合成に関与する環化酵素遺伝子のクローニングと機能解析(口頭発表,植物化学調節学会第41回大会)
- 3B04 コンビナトリアル合成法によるベンゼノイド液晶化合物の探索(化学・材料)
- 蛍光ディップ法による5-フェニルトロポロンの分子内プロトン移動の解析
- PAb03 光散乱法を利用した液晶分子の相転移温度の評価(1)
- Synthesis and properties of 2-bromo-7-(1,4,7,10-tetraoxa-13-azacyclopenodec-13-yl)-2,4,6-cycloheptatrien-1-one
- Synthesis and mercurophilic properties of of dithiocrown ethers having an azulene pendant
- Synthesis and Properties of Columnar Liquid Crystals and Organogelator with a Bitropone Core
- Synthesis and Properties of Cholesteryl Benzoate Derivatives : Liquid Crystals and Organogelators
- Synthesis and Mesomorphic Properties of Tropon-4-yl 4-n-Alkoxybenzoates : Roles of a Tropone Ring as a Polar Terminal Group
- Synthesis, Complexation Behaviors, and Crystal Structures of Azamacrocycles Having Tropon-2-yl Groups
- Synthesis, Structure, and Mesomorphic Properties of Liquid Crystals with a Bitropone Core
- Synthesis, Crystal Structures and Mesomorphic Properties of Liquid Crystals with a N,N'-Bis(tropon-2-yl)piperazine Skeleton
- Synthesis and Complexation Behavior of Diaza-18-crown-6 Having Troponyl and Anthryl Groups
- Synthesis and Properties of Diazacrown Ethers Carrying Two Tropone Chromophores
- Complexation and Fluorescence Behavior of Tris[(1-naphthoyloxy)ethyl]amine
- Lead(IV) Oxide-Mediated Oxidation of Azulen-2-ols to Form 1,1-Coupled Dimers and Hexacyclic Cage-Dimers
- Novel Non-benzenoid Electron Acceptors:Syntheses and Electron Acceptability of Tetracyanoazulenequinodimethanes and Dicyanoazulenequinonemethides
- A New Mercurophilic Troponoid Tetrathiacyclophane;2, 6, 8, 12-Tetrathia-1(2, 7), 7(2, 7)-ditropona-4(1, 3), 10(1, 3)-dibenzenacyclododecaphane
- Crystal Structures of Mercury(II)Dichloride Complexes of 5,8-Dioxa-2,11-dithiabicyclo[10.4.1]heptadeca-1(16),12,14-trien-17-one and 5,8,11-Trioxa-2,14-dithiabicyclo[13.4.1]icosa-1(19),15,17-trien-20-one
- Synthesis of 9-Deoxycotylenol Derivatives Carrying a Fluorescent Chromophore
- 96(P14) 9-デオキシコチレノール誘導体の合成と活性(ポスター発表の部)
- Synthetic Studies on Dolabellane Diterpenoids. Synthesis of 10-epi-Clavudiol A, an Epimer of a Marine Dolabellanoid
- Synthesis and Properties of Bis(5-alkoxytropolonato) Metallomesogens
- トリチルカチオン生成反応に及ぼすリチウムイオンの求電子反応性の定量化
- モモ枝折病菌 (Phomopsis amygdali) Niigata 2 からのフシコクシン類の化学的同定とそれによる 3′-デアセチルフシコクシン A の生産
- The High-Pressure Cycloadditions of Tropone to Styrenes. Predominant Formation of [8+2] Cycloadducts from α-Methylstyrene
- High-Pressure Diels-Alder Reaction of Tropone Acetal with Several Dienophiles
- The ^C NMR Chemical Shift Comparisons of Dihydrohomobarrelenones
- Synthesis and Mesomorphic Properties of Liquid Crystals with a 5,5'-Bitropolone Skelton
- 3PD02 5-(4-置換フェニルアゾ)トロポロン誘導体の液晶性
- 1C02 2-アミノベンゾイル-5-アルコキシトロポン誘導体の液晶性に対するベンゾイル基上の置換基効果
- シグマトロピー転位型および水素結合型トロポノイド液晶化合物の構築
- 1A03 2-(4-アルコキシパーフルオロベンゾイルオキシ)-5-アルコキシトポロンの液晶性
- 1B503 5-フェニルトロポン骨格をコアに持つ液晶の合成 : 第2報
- B-21 Fusicoccane化合物の寄生雑草種子発芽刺激活性における構造要求性
- Electronic Spectra of Jet-Cooled 3- and 4-Chlorotropolones : Influence of Asymmetric Substitution on the Intramolecular Hydrogen Bonding
- Crystal Structures on N, N'-Bis(1-naphthylmethyl)-1,4,10,13-tetraoxa-7,16-diazacylooctadecane Complexed with Potassium and Barium Thiocyanates
- Synthetic Photochemistry. LXXI. Photocycloaddition of Methyl 2,4-Dioxohexanoate to 3-Benzylozy-2-methylpropene
- Synthesis and Complexation Behavior of Diaza-18-crown-6 Carrying Two Pyrenylmethyl Groups
- Synthesis of 9-Deoxycotylenol Derivatives and Their Seed Germination-Stimulating Activity
- Mercurophilic 1-(8,8-Dicyanoheptafulven-3-yl)aza-15-crown-5 Ether. Synthesis, X-Ray Structural Analysis, and Fixation of Its Derivative on a Polymer
- Inner Rotation of the Exocyclic C=C Bonds of Methyl 2-Cyano-(2-methyl-cyclohepta[b]thiophen-8-ylidene)acetate and Methyl 2-Cyano-(1,2-dimethylcyclohepta[b]pyrrol-8-ylidene)acetate
- A New Convenient Synthesis of 1,2′-Biazulenes by Photolysis of 2-Diazo-1,3-dicyanoazulen-6(2H)-one with Azulene Derivatives
- リチウムイオンによって加速されたクアドリシクランからノルボルナジエンへの原子価異性化反応
- Synthetic Photochemistry. LIX. Intramolecular Photocycloaddition of 2-(3-Butenyl)-2, 6-dimethyl-4H-1, 3-dioxin-4-one
- Preparation of Sigmatropic 2-Acyloxy-5-perfluoroalkoxytropones : New Monocyclic Troponoid Liquid Crystals with an Enantiotropic Smectic A Phase
- 7 フシコクシン型ジテルペン配糖体の抗がん活性(口頭発表の部)
- 14. モモ枝折病菌(Phomopsis amygdali)による植物成長物質フシコクシンの発酵生産と生理活性(第35回大会研究発表抄録)
- 14 モモ技折病菌(Phomopsis amygdali)による植物成長物質フシコクシンの発酵生産と生理活性
- A116 本邦産モモ枝折病菌 Phomopsis amygdali は植物成長物質フシコクシンを生産する
- 特異な生理活性菌類ジテルペン配糖体-フシコクシン, エリナシン-における初期生合成経路の解明と応用
- B-20 H^+-ATPアーゼ活性化物質フシコクシンJの新誘導体の分離と同定
- Synthesis of 9-Deoxy-15-hydroxycotylenol and Its Germination-Stimulating Activity on Lettuce Seeds
- Photodimerizations of 1,5- and 1,7-Azulenequinones : Solvent, Substituent, and Concentration Effects on the Product Distribution
- フシコッカジエン誘導体のフシコクシン生産菌による代謝変換--フシコクシ生合成初期過程に対する考察
- 有機低分子による細胞内信号伝達経路の解明と制御(平成13年度 機能研所長リーダーシップ経費(若手奨励研究)による研究の紹介)
- Total Synthesis of Sollasin a and Sollasin d via Photocycloaddition of Methyl 2, 4-Dioxopentanoate to Methyl E-2-Methyl-2-butenoate
- Synthetic Photochemistry. LXX. Efficient Formation of An Eudesmane Skeleton by the de Mayo Reaction between 1-Isopropyl-4-methylcyclohexa-1,3-diene and Methyl 2,4-Dioxopentanoate
- Synthesis of Bis (2, 6-dihydroxy-5-oxo-1, 3, 6-cycloheptatrienyl) methane from 2-Alkoxy-5-hydroxytropones and the Electrochemical Properties of Bis (3, 4, 7-trioxo-1, 5-cycloheptadienyl)- methane Derivatives
- Addition Reaction of 2-Pyrone-5-carboxylate with α-Terpinene. An Attempted Conversion of Monoterpene to Sesquiterpenoids
- Collision-Activated Dissociation Spectra for the Characterization of the Diels-Alder Adducts between C_ and Troponoids
- Highly Thermally-Stable Diels-Alder Adducts of [60]Fullerene with 2-Cycloalkenones and Their Acetals
- Mass-Spectral Fragmentation Spequences of Thienotropone 1,1-Dioxides
- Synthetic Photochemistry-36-A Formal Total Synthesis of Silphinene from Methyl 8-Methyl-2,4-dioxonon-7-enoate by Intramolecular Photocycloaddition
- Photoaddition Reaction of Methyl 2,4-Dioxopentanoate with Chloroprene
- Preparation of Tetraphenylazulenequinodimethanes from the Reactions of Azulenequinones with Diphenylketene and the ^1H NMR and UV-vis Spectral Studies in Acidic Media
- New Troponoid Liquid Crystalline Compounds, 5-Alkoxy-2-(4-alkoxybenzoylamino)tropones
- Synthesis and Mercurophilic Properties of 2,2'-Oxybis(ethylenethio)ditropone and α-[2-(2-Troponylthio)ethyl]-ω-(2-troponylthio)oligo(oxyethylene)
- Photodimerizations of 3-Methoxy-1, 5-azulenequinone via Consecutive Pericyclic Reactions
- High-Pressure Diels-Alder Reaction of [C60] Fullerene with Functionalized Tropone Derivatives
- Condensation of Polyfluoroalkanols to Tropolone to Form 2-(Polyfluoroalkoxy) tropones and Their High-Pressure Diels-Alder Reaction with [60] Fullerene
- High-Pressure Diels-Alder Reaction between Buckminsterfullerene and Tropone
- Geometrical Isomerism of the Exocyclic C=C Bonds of Heptafulvene Derivatives. Steric and Electronic Effects on the Rotational Barrier
- Mild Intramolecular Thermal Rearrangements of 2-(2-Propynylsulfinyl) tropone and Its Homologues to Cyclohepta[b]thiophen-8-ones
- 49 真菌が生産する植物生長物質コチレニンAの構造確認とコチレノール新誘導体の同定
- High-Pressure Diels-Alder Reaction of Cyclooctatetraene with Dimethyl 1,4-Dimethyl-7-oxabicyclo[2.2.1]hepta-2,5-diene2,3-dicarboxylate. Single Crystalline State Valence Isomerization of a syn-Tricyclo[4.2.0.0^]octane Derivative
- A Formal Total Synthesis of Colchicine via the Scott's Intermediate. Palladium (0)-Mediated meta-Ethynylation of a Tropolone Derivative
- Synthetic Photochemistry. XLIII. Chromium (II) Chloride-Mediated Reductive Condensations of (3S)- and (3R)-1-Iriden-7-als with (3S)-7-Chloro-1-iridenes. ^1H NMR Spectral Differentiation of the Stereochemistry
- 1D09 5-アルコキシ-2-(4-アルコキシベンゾイルアミノ)トロポンの液晶性発現とCH-π相互作用
- Synthetic Photochemistry. LXIX. The Structures of the Photocycloadducts of 2-Acetoxy-4, 4-dimethylbutenolide with Cyclohexene : A Revision
- Synthesis and Properties of 1-(Tropon-2-yl)-1-aza-4,7,10,13-tetraoxacyclopentadecanes. Preferential Complexation of Lithium Salt among the Alkali Salts
- Preferential Coordination of Mercury(II) Chloride to Ethereal Oxygens over Sulfurs in 23-Dicyanomethylene-5,8,11,14,17-pentaoxa-2,20-dithiabicyclo[19.4.1]hexacosa-1(26),21,24-triene and 20-Dicyanomethylene-5,8,11,14,-tetraoxa-2,17-dithiabicyclo[16.4.1]tri
- Synthesis and Mercurophilic Properties of Bis (2-troponyl) Thioethers of Di-, Tri-, and Tetraethylene Glycols
- Synthetic Photochemistry. LXVI. The Photoaddition of 2-Oxo-γ-valerolactone to Cyclohexene
- Construction of Functionalized Dolabellane Framework via the Stereocontrolled Cope Rearrangement of a 1,3,2-Dioxasilacycloheptane Derivative
- A Total Synthesis of (±)-Sativene via High-Pressure Diels-Alder Route
- Total Synthesis of Optically-Active Shizuka-acoradienol by Means of High-Pressure Diels-Alder Reaction
- Photoaddition Reaction of Methyl 2,4-Dioxopentanoate with 1,3-Butadiene
- 5-8-5員環系高級テルペノイドの全合成
- Electrochemical Oxidation of 5-Hydroxytropolone
- Cycloaddition-Cycloreversion Sequence for One-pot Preparation of Dibenzobarrelene and Janusene Derivatives from Anthracenes and 2,3-Bis (methoxycarbonyl)-7-oxanorbornadiene
- Intramolecular Disproportionation Reactions of 4,6-Bis (chloromethyl) -2,5-dimethoxytropone via Heptafulvene Intermediates
- Synthesis of 4, 6-Dicyano-2, 5-dimethoxytropone
- Diels-Alder Reactions of Fullerene C_ and 4-Hydroxytropones
- PB71 SYNTHESIS OF 5-8-5-MEMBERED TRICYCLIC TERPENOIDS AND THEIR B-SECO-RELATED COMPOUNDS
- Synthetic Photochemistry. XLVIII. Stereocontrolled Generation of the Ophiobolane Type 5-8-5-Membered Tricyclic Ring System
- 近畿支部 : 産学連携・雑感
- 26. フシコクシンによる種子発芽促進機構に関する研究-第2報(口頭発表,植物化学調節学会第47回大会)
- 27. bZIP 型転写因子と14-3-3 相互作用に対するフシコクシンの影響(口頭発表,植物化学調節学会第47回大会)
- 83. bZIP型転写因子と14-3-3相互作用に対するフシコクシンの影響 第2報(口頭発表,植物化学調節学会第48回大会)