Synthetic photochemistry LV. Characterization of the lumiketone-type photoproducts, bicyclo(3.2.0)hept-3-en-2-ones, from 2,6-cycloheptadien-1-ones.

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概要

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• Unlike the parent 2,6-cycloheptadien-1-one, the UV-light irradiation of polysubstituted 2,6-cycloheptadien-1-ones gave bicyclo[3.2.0]hept-3-en-2-ones, lumiketone-like products, which subsequently photoisomerized to bicyclo[2.2.1]hept-2-en-7-ones. The reaction of cycloheptadienones to lumiketones was proven to proceed via a triplet excited state from both sensitization and quenching experiments.

• 公益社団法人 日本化学会の論文

著者

• Takeshita Hitoshi

  Institute Of Advanced Material Study 86 Kyushu University

• Ikeda Yukari

  Institute Of Advanced Material Study 86 Kyushu University

• Mori Akira

  Institute For Materials Chemistry And Engineering Kyushu University

• Kubota Tadahiko

  Graduate School of Engineering Sciences, 39, Kyushu University

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