Pressure-accelerated Diels-Alder reactions of tropones with aromatic p-quinones.

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概要

• 論文の詳細を見る

• The Diels–Alder reactions of tropones with aromatic <I>p</I>-quinones under 3000 and 10000 bar gave enolized 1:1-adducts together with dehydrogenated products, homobarrelenone derivatives. The latter were isomerized to tetracyclo[6.5.0.0<SUP>1,9</SUP>.0<SUP>5,9</SUP>]trideca-2,6,11-triene-4,10,13-triones on exposure to diffused light. No cycloadduct was obtained when the reaction was carried out under 1 bar.

• 公益社団法人 日本化学会の論文

著者

• Takeshita Hitoshi

  Institute Of Advanced Material Study 86 Kyushu University

• Mori Akira

  Institute For Materials Chemistry And Engineering Kyushu University

• Nakashima Hisataka

  Graduate School of Engineering Sciences, 39, Kyushu University

• Li Zhi-Hong

  Graduate School of Engineering Sciences, 39, Kyushu University

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