Crystal Structure and Complexation and Fluorescence Behaviors of 1,4-Bis (9-anthracenylmethyl) piperazine
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概要
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The crystal structure of the photoinduced electron transfer (PET) fluoroionophore (3) was clarified by X-ray crystallographic analysis. A molecule 3 sits on a center of symmetry such that two anthracene ring systems are in an anti conformation with respect to one another across the piperazine ring. Intermolecular C-H···π and π···π interactions are observed. It was found that 3 was displayed unique photophysical properties in the presence of guest cations. Complexation of 3 with Zn2+ and NH4+ increased the fluorescence intensities of the host by a factor of 20.
著者
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SAKURAI Tadamitsu
Department of Applied Chemistry, Faculty of Engineering, Kanagawa University
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Sakurai Tadamitsu
Department Of Applied Chemistry Faculty Of Engineering Kanagawa University
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Sakurai Tadamitsu
Department Of Material And Life Chemistry Faculty Of Engineering Kanagawa University
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Igarashi Tetsutaro
Department Of Material And Life Chemistry Faculty Of Engineering Kanagawa University
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MATSUMOTO Taisuke
Institute for Materials Chemistry and Engineering, Kyushu University
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Kubo Kanji
School of Dentistry, Health Sciences University of Hokkaido
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TAKECHI Haruko
Faculty of Pharmaceutical Sciences, Health Sciences University of Hokkaido
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Takahashi Hajime
Faculty of Pharmaceutical Sciences, Health Sciences University of Hokkaido
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Takechi Haruko
Faculty Of Pharmaceutical Sciences Health Sciences University Of Hokkaido
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Hayakawa Akinori
Department of Material Life Chemistry, Faculty of Engineering, Kanagawa University
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Matsumoto Taisuke
Institute For Materials Chemistry And Engineering Kyushu University
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Takahashi Hajime
Faculty Of Engineering And Resource Science Akita University
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Igarashi Tetsutaro
Department of Material Life Chemistry, Faculty of Engineering, Kanagawa University
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Igarashi Tetsutaro
Department of Applied Chemistry, Faculty of Technology, Kanagawa University
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