Reaction of N-aroyl-N-arylhydroxylamines with o-nitrobenzenesulfenyl chloride.
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概要
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Reactions of <I>N</I>-aroyl-<I>N</I>-arylhydroxylamines with <I>o</I>-nitrobenzenesulfenyl chloride were found to afford the corresponding <I>N</I>-aroylarylamines and <I>S</I>-(<I>o</I>-nitrophenyl) <I>o</I>-nitrobenzenethiosulfonate in good yields, respectively. Both the product distributions and the effect of substituents on the amount of reduction product suggest these reactions to proceed <I>via</I> homolytic cleavage of the N–O bond.
- 公益社団法人 日本化学会の論文
著者
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Sakurai Tadamitsu
Department Of Applied Chemistry Faculty Of Engineering Kanagawa University
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Oae Shigeru
Institute of Chemistry, The University of Tsukuba
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