The photochemical reaction of benzo(c)cinnoline. IV. Comments on the mechanism of 2,2'-diaminobiphenyl formation.

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概要

• 論文の詳細を見る

• In order to determine the mechanism of 2,2′-diaminobiphenyl formation from benzo[<I>c</I>]cinnoline, effect of aldehyde on the reaction was examined. It is proposed that ethanal, which was generated from ethanol in the initial photoreduction, formed an adduct with 5,6-dihydrobenzo[<I>c</I>]cinnoline, and that the resulting adduct participated in the subsequent photo-induced 2,2′-diaminobiphenyl formation.

• 公益社団法人 日本化学会の論文

著者

• Sakurai Tadamitsu

  Department Of Applied Chemistry Faculty Of Engineering Kanagawa University

• Inoue Hiroyasu

  Department Of Applied Chemistry Faculty Of Technology Kanagawa University

• Hiroshima Yukimi

  Department of Applied Chemistry, Faculty of Technology, Kanagawa University

• Sakai Toshihiko

  Department of Applied Chemistry, Faculty of Technology, Kanagawa University

• Fukuda Norio

  Department of Applied Chemistry, Faculty of Technology, Kanagawa University

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