Tertiary amine-catalyzed acyl group-exchange reactions of N,O-diacyl-o-aminophenols.
スポンサーリンク
概要
- 論文の詳細を見る
A kinetic study on the base-catalyzed acyl group-exchange reactions of <I>N</I>,<I>O</I>-diacyl-<I>o</I>-aminophenols was undertaken to show that the formation of the amidate ion should be the rate-determining step in these intramolecular acyl-exchange reactions, and that the electron-withdrawing power of acyl group becomes an important factor to control the relative stabilities of a pair of <I>N</I>,<I>O</I>-diacyl-<I>o</I>-aminophenols.
- 公益社団法人 日本化学会の論文
著者
-
Yamada Shuichi
Department Of Neurosurgery Nara Medical University
-
Sakurai Tadamitsu
Department Of Applied Chemistry Faculty Of Engineering Kanagawa University
-
Inoue Hiroyasu
Department Of Applied Chemistry Faculty Of Technology Kanagawa University
-
Yamada Shuichi
Department of Applied Chemistry, Faculty of Technology, Kanagawa University
関連論文
- 小児期に骨髄移植を受けた患児の甲状腺機能の変化
- The Kinetics of Immune Reconstitution after Cord Blood Transplantation and Selected CD34^+ Stem Cell Transplantation in Children : Comparison with Bone Marrow Transplantation
- Complexation and Fluorescence Behavior of Tris[(1-naphthoyloxy)ethyl]amine
- CoCl_2 Inhibits Neural Differentiation of Retinoic Acid-Treated Embryoid Bodies(CELL AND TISSUE ENGINEERING)
- Crystal Structure and Complexation and Fluorescence Behaviors of 1,4-Bis (9-anthracenylmethyl) piperazine
- The Generation of Immunocompetent Dendritic Cells From CD34^+ Acute Myeloid or Lymphoid Leukemia Cells
- Synthesis and Complexation Behavior of Diaza-18-crown-6 Carrying Two Pyrenylmethyl Groups
- Progressive multifocal leukoencephalopathy after allogeneic bone marrow transplantation for Wiskott-Aldrich syndrome
- Proton-Transferred Ion Pairs of p-Hydroxybenzaldehyde and p-Hydroxyacetophenone in Ethers at Low Temperature
- Refolding and Activation of Human Prorenin Expressed in Escherichia coli : Application of Recombinant Human Renin for Inhibitor Screening
- Association Behavior of 1-Pyrenyl Pendants Introduced into the Papain Active Site
- The Role of α-Chymotrypsin Active Site in the Proton Dissociation of Aromatic Sulfonium-Salt Pendants Attached to the Methionine-192 Residue
- Self-Sensitized Photolysis of N-(1-Naphthoyl)-N-phenyl-O-(benzoyl-substituted benzoyl)hydroxylamines
- Complexation and Fluorescence Behavior of Diaza-15-crown-5 Carrying Two Naphthyl Pendants
- Modulated differentiation of embryonic stem cells into hepatocyte-like cells by coculture with hepatic stellate cells(CELL AND TISSUE ENGINEERING)
- Mechanism of the Benzophenone-Sensitized Photolysis of O-Benzoyl-N-(1-naphthoyl)-N-phenylhydroxylamine in Cationic Micellar Media
- Absorption and Phosphorescence Spectra of Xanthone : Dimer and Tetramer Formations at Low Temperatures
- Observation of Domain Structure in Triglycine Sulfate by a Pyroelectric Probe Technique
- Cervical Extradural En-plaque Meningioma : Case Report
- 1-(Arylmethyloxy)-9,10-anthraquinones : Photoinitiators for Radical and Cationic Polymerizations
- Functional Expression of Miraculin, a Taste-Modifying Protein in Escherichia Coli
- Imine-Forming Radical Elimination Reactions of O-(1-Naphthoyl)-N,N-bis(p-substituted benzyl)hydroxylamines Activated by Triplet Benzophenone
- Synthesis and Complexation Behavior of 2-[N, N-Bis (1-naphthylmethyl)-aminomethyl]-18-crown-6
- Evaluation of Combined Use of Transcranial and Direct Cortical Motor Evoked Potential Monitoring During Unruptured Aneurysm Surgery
- Citronellol and Geraniol, Components of Rose Oil, Activate Peroxisome Proliferator-Activated Receptor α and γ and Suppress Cyclooxygenase-2 Expression
- Base-Catalyzed Acyl Exchange Reactions of N,O-Diacyl-o-aminophenols. Substituent and Temperature Effects on the Equilibrium Constants
- Synthesis and Properties of N, N'-Bis(1-pyrenylmethyl)-1, 4, 10, 13-tetraoxa-7, 16-diazacyclooctadecane. Metal Ion-Induced Monomer and Excimer Emission Enhancement
- Recent Advances in the Study on Resveratrol
- 1-(Arylmethyloxy)anthracenes : how substituents affect their photoreactivity and ability to initiate radical and cationic polymerizations
- Evaluation of Food-derived Functional Ingredients According to Activation of PPAR and Suppression of COX-2 Expression
- Cavernous Malformations in Pregnancy
- The photochemical reaction of benzo(c)cinnoline. IV. Comments on the mechanism of 2,2'-diaminobiphenyl formation.
- Intersystem Crossing of Radical Pair in Solvent Cage. External Heavy Atom Effect on Dual Photoreactions of Phthalazine.
- Mechanism of the pyrene-sensitized photolysis of N-(1-naphthoyl)-O-(p-toluoyl)-N-phenylhydroxylamine.
- The Polarized Absorption Spectra of Some β-Substituted Anthraquinones
- The Polarized Absorption Spectra of Some α-Aminoanthraquinones
- Electronic Spectra of Biphenyl and Fluorene
- The Dichroic Spectra of Hydroxy Derivatives of Naphthalene, Anthracene, and Phenanthrene in Polyvinylalcohol Sheets
- Photochemical reactions of phthalazine in 2-propanol.
- Tertiary amine-catalyzed acyl group-exchange reactions of N,O-diacyl-o-aminophenols.
- Intracranial Meningioma as Initial Clinical Manifestation of Occult Lung Carcinoma: Case Report
- Proton-transferred ion pairs of p-hydroxybenzaldehyde and p-hydroxyacetophenone in ethers at low temperature.
- Elimination and nucleophilic substitution on nitrogen atom. Reactions of -O-aroyl-N,N-di(p-substituted benzyl)- and O-aroyl-N-benzoyl-N-benzylhydroxylamines with various nucleophiles in dipolar aprotic solvents.
- The photolysis of N,O-diacyl-N-phenylhydroxylamines.
- Benzophenone-Sensitized Photolysis of N,N-Dibenzyl-O-acylhydroxylamines. Mechanism of the Imine-Forming Radical Elimination Reaction.
- Reaction of N-aroyl-N-arylhydroxylamines with o-nitrobenzenesulfenyl chloride.
- A Novel Reduction of the O-(3,5-Dinitrobenzoyl)-N,N-(aroylary)hydroxylamines by the Cyanide Ion in Dipolar Aprotic Solvents
- Tertiary amine-catalyzed acyl group exchange reaction of N,O-diacyl-o-aminophenols. Its mechanism and factors determining the relative stability of acyl exchanged isomer pairs.
- Spectrophotometric Studies of the Acidities of Dichlorophene and Hexachlorophene
- Prospect of Micro Power Generation Utilizing VIV in Small Stream Based on Verification Experiments of Power Generation in Water Tunnel
- The Photochemical Reaction of Benzo[c]cinnoline. I. The Photoreduction and Subsequent Reactions in Acidified Alcohols
- The Solvent Effect on the Stability of α-Pyridoin
- Intramolecular Charge-transfer Interaction in Substituted Diphenylmethanes
- Cavernous Malformations in Pregnancy
- Photoinduced Large Increase in the Refractive Index of N-2-Thenoyloxyary1-4-tert-butylphenoxyacetamide Film
- Photoinduced refractive-index change in 4-tert-butylcalix[8]arenes bearing N-acyloxyphenylamide chromophores
- Growth and Endocrine Function in Long-term Adult Survivors of Childhood Stem Cell Transplant
- Evaluation of Food-derived Functional Ingredients According to Activation of PPAR and Suppression of COX-2 Expression