ON ADSORBABILITY OF "MISO"CONTAINED IN "OHYA-ISHI"

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概要

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• Ohya-ishi is Miocene tuff breccia occurring in Ohya district, Utsunomiya, Tochigi Prefecture, Japan. The matrix of the Ohya-ishi is mainly composed of clinoptilolite, a kind of zeolite. It also contains many kinds of fragments, among which so-called "miso"is the most conspicuous. This is composed of intimate mixture of iron-rich saponite and iron-poor montmorillonite-beidellite. Physical properties of powders of Ohya-ishi, miso and heated miso were investigated by the DTA method, etc. Their adsorption capacity was determined by methylene blue and ammoniacal nitrogen, and also relations between the adsorption capacity and composition of the contained minerals were investigated by the X-ray powder diffraction method. As a results, methylene blue is much more adsorbed by miso than by the powder of Ohya-ishi, and ammoniacal nitrogen is more adsorbed by the powder of Ohya-ishi than miso. It seems that the clay minerals contained in the powder of Ohya-ishi and miso is mixture of montmorillonite and iron-saponite, and since miso contains more iron, it seems that miso contains more iron-saponite. After heating miso, adsorption of both methylene blue and ammoniacal nitrogen is reduced. Both powder of Ohya-ishi and miso have a higher decoloration of an aqueous methylene blue solution and can be used well as a commercial adsorbent.

• 日本粘土学会の論文

著者

• Tanaka Hajime

  Department Of Applied Physics Faculty Of Engineering University Of Tokyo

• Tanaka H

  Department Of Applied Chemistry Faculty Of Engineering Utsunomiya University

• Tohgoh Hiroshi

  Department Of Industrial Chemistry Faculty Of Engineering Utsunomiya University

• KAWATA TATSUO

  Department of Industrial Chemistry, Faculty of Engineering, Utsunomiya University

• Kawata Tatsuo

  Department Of Industrial Chemistry Faculty Of Engineering Utsunomiya University

• Tanaka Hajime

  Department Of Applied Physics And Applied Mechanics Institute Of Industrial Science University Of To

• Tanaka Hajime

  Department Of Industrial Chemistry Faculty Of Engineering Utsunomiya University

• TANAKA HAJIME

  Department of Applied Chemistry, Faculty of Engineering, Utsunomiya University

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