有機硫黄化合物の研究(第3報)cis-およびtrans-1-Thioniabicyclo-[4.4.0]decane Bromideの反応

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概要

• 論文の詳細を見る

• Solutions of II (ylid of I) were prepared by treatment of 1-thioniabicyclo [4. 4. 0] decane bromide (I) with sodium hydride in nitrogen at refluxing temperature in abs. tetrahydrofuran. The reaction of II with carbonyl compounds and active methylene compounds was examined and in all cases examined, II reacted with the carbonyl and active methylene compounds at its 2-position to give the corresponding epoxides and monosubstituted active methylene compounds, respectively. The reaction of II with 1/2 molar equivalent of malononitrile gave a disubstituted malononitrile in a good yield.

• 公益社団法人日本薬学会の論文
• 1978-08-25

著者

• 荒田 義雄

  Faculty Of Pharmaceutical Sciences Kanazawa University

• 板谷 芳京

  金沢大学薬学部

• 徳野 健次

  金沢医科大学

• 大橋 力

  金沢医科大学

• 三由 文久

  金沢医科大学

• 荒川 良夫

  金沢大学薬学部

関連論文

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