1-Azabicyclo化合物の研究 その6 : Octahydroquinolizineの1改良合成法ならびにその脱水素化反応について
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概要
- 論文の詳細を見る
Catalytic reduction of ethyl 2-ethoxycarbonyl-4- (2-pyridyl) butanoate (I) over platinum・rhodium followed by distillation led to III which, on heating with barium hydroxide, gave V in good yield. The action of N-bromosuccinimide on VI derived from V afforded IX. An N-oxide (X) derived from VI was warmed in a tartaric acid solution containing ferric nitrate to give VIII and IX.
- 公益社団法人日本薬学会の論文
- 1969-03-25
著者
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山田 順子
金沢大学薬学部医療薬学講座
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荒田 義雄
金沢大学薬学部
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荒田 義雄
Faculty Of Pharmaceutical Sciences Kanazawa University
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林 保子
金沢大学薬学部
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塩田 登美子
金沢大学薬学部
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山田 順子
金沢大学薬学部
関連論文
- P-483 金沢大学薬学部における早期体験学習
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- Studies on 1-Azabicyclo Compounds. XXVI. Synthesis of Ten-membered Ring Amines from 9a-Cyanomethyl-, 9a-Ethoxycarbonylmethyl-, and 1-Ethoxycarbonyl-octahydroquinolizine
- Studies on 1-Azabicyclo Compounds. XXVIII. Synthesis of 1-Methyl-perhydroazocin-5-one from Pyrrolizidine
- Synthesis of (±)-Methyldecamine
- 双環状アミン体から中環状アミン類の合成
- Synthetic Studies on Lythraceae Alkaloids. V. Total Synthesis of (±)-Vertaline
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- Total Synthesis of (±)-Lagerine
- Synthetic Studies on Lythraceae Alkaloids. III. Stereoselective Total Synthesis of (±)-Decaline
- Synthetic Studies on Lythraceae Alkaloids. II. The Mannich Reaction of Isopelletierine with 3-Methoxybenzaldehyde and 3-Hydroxybenzaldehyde
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- Studies on 1-Azabicyclo Compounds. XXII. Stereochemistry of 9a-Substituted Quinolizidine Methiodides
- Studies on 1-Azabicyclo Compounds. XIX. Synthesis of Ten-membered Ring Amine Derivatives from 5-Methyl-10-nitromethyloctahydro-quinolizinium Iodide and Its Derivatives
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- Studies on 1-Azabicyclo Compounds. XIII. Synthesis of 1-Methyl-6-decahydroazecinone by the Reaction of 3,4,6,7,8,9-Hexahydro-2H-quinolizine with Methyl Iodide
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- Constituents of Rhizoma Nupharis. XXVI. Carbon-13 Nuclear Magnetic Resonance Spectra of Nupharamine, Anhydronupharamine, Nuphamine, and Related Compounds
- 26 Lythraceaeアルカロイドの合成 : (±)-Decaline,(±)-Vertaline,(±)-Desmethyldecaline,(±)-Methyldecinine,(±)-Methyllagerineの全合成
- 1-Azabicyclo 化合物の研究 (第23報) Deoxynupharidine の酢酸水銀酸化について
- Studies on 1-Azabicyclo Compounds. XII. Synthesis of 5,6,8,9,10,11,11a, 12-Octahydroindolo [3,2-b] quinolizine and Related Compounds
- Constituents of Rhizoma Nupharis. XXV. Formation of Dehydro-deoxynupharidine from Nupharidine
- 川骨成分の研究(第24報) : 新アルカロイド Anhydronupharamine について
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- Synthesis of (±)-Desmethyldecaline
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- Synthesis of (±)-Methyldecinine
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- 有機硫黄化合物の研究cis-およびtrans-1-Thioniabicyclo[4.4.0]-decane Bromideの分離および反応
- Constituents of Rhizoma Nupharis. XXIII. The Absolute Configuration of Nuphamine
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- Studies on 1-Azabicyclo Compounds. XXVII. Synthesis of Ten-membered Ring Amines from 1-Oxo-, 9a-Benzyl-, and 9a-Benzyl-1-oxo-quinolizidine
- Chemical Transformation of Protoberberines. III. Convenient Synthesis of 8-Methoxyberberinephenolbetaine by Photooxygenation of Berberine. A Novel Conversion of Berberine into (±)-Ophiocarpine, (±)-Epiophiocarpine, (±)-α-Hydrastine, and (±)-β-Hydrastine
- Chemical Transformation of Protoberberines. I. Conversion of Tetrahydroberberine and Dihydroberberine into Noroxyhydrastinine by Photooxygenation
- 53 Berberine及びその誘導体の光酸素化反応と関連アルカロイドへの変換
- 1-Azabicyclo化合物の研究 その6 : Octahydroquinolizineの1改良合成法ならびにその脱水素化反応について
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- Studies on 1-Azabicyclo Compounds. XVII. Transannular Reaction of cis- and trans-1,2,3,4,7,8,9,10-Octahydroazecine and Their Derivatives
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