金属イオン{M}-有機試薬{R}反応を用いる光分析法

概要

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Firstly, the syntheses of various organic reagents{R}containing such xanthene derivtives as O-hydroxyhydroquinonephthalein(QnPh), and 3, 4, 5, 6-tetrahydroxyfluoran(gallein, Gall)were studied. Secondarily, the coexisting effects of surfactant(cationic-, anionic-, amphoteric- and nonionic-surfactants alone or combination)on the coloring or fluorescence reactions between various{R}such as xanthene derivatives, aromatic amines and various metal ions{M}such as bismuth(III), tin(IV), iron(III), molybdenum(VI), uranium(VI), cobalt(II), aluminum(III), etc.were systematically investigated. Thirdly, numerous simple and sensitive photometric analyses(spectrophotometry and fluorophotometry)for various{M}and organic compounds{Org}such as biological samples, and pharmaceutical preparations by formation reactions of{R-M}binary or{(R-M)-Org}ternary complexes were established in the coexistence of surfactant alone or combination.
公益社団法人日本薬学会の論文
2001-10-01