Metal Isotope Effects on the Vibrational Spectra of Polymeric Metal Complexes. II. Infrared Spectra of Copper and Zinc Glutamate Dihydrates
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概要
- 論文の詳細を見る
The infrared spectra of [Cu (glutamate)・(H_2O)]_n・(H_2O)_n, [Zn (glutamate)・(H_2O)]_n・(H_2O)_n and their isotopic complexes containing metal and hydrogen isotopes have been measured in the region between 4000 and 200 cm^<-1>. The isotope shifts on ^<63>Cu and ^<65>Cu substitution have been observed for bands at 404,352 and 279 cm^<-1> of the Cu complex. Bands at 300,245 and 227 cm^<-1> of the Zn complex are apparently sensitive to ^<64>Zn and ^<68>Zn substitution. The frequency shifts on N, O-deuteration indicated that a Cu-OOC stretching vibration is localized for the Cu complex whereas Zn-OOC stretching vibrations couple with Zn-NH_2 and/or Zn-OH_2 stretching vibrations.
- 公益社団法人日本薬学会の論文
- 1982-08-25
著者
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尾堂 順一
Faculty of Pharmaceutical Sciences, Okayama University
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田中 善正
Faculty of Pharmaceutical Sciences, Okayama University
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斎藤 寛
Department Of Pharmaceutical Sciences Graduate School Of Medicine And Dentistry And Pharmaceutical S
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斎藤 寛
岡山大・薬
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西尾 政晃
Faculty of Pharmaceutical Sciences, Okayama University
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SAITO YUTAKA
Faculty of Pharmaceutical Sciences, Okayama University
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田中 善正
Faculty Of Pharmaceutical Sciences Okayama University:(present Address)department Of Biochemistry Co
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田中 善正
Faculty Of Pharmaceutical Sciences Okayama University
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Saito Yutaka
Faculty Of Engineering Kanazawa University
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