Photoreaction Generating Active Oxygens of In^3+-Tetrakis(4-methylpyridyl)-porphine in the Presence of Albumins
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概要
- 論文の詳細を見る
The complex formation of In^3+-tetrakis(4-N-methylpyridyl)-porphine (In-TMPyP) with albumin was studied by resonance Raman spectroscopy. Albumin coordinated to In^3+ through the -S^- group(s). The photoreaction was investigated using the visible spectral change and In-TMPyP-thiourea complex was used as a model. It was demonstrated that the complex in a weak basic solution (pH 8.5) is excited by light and the excited complex converts oxygen to superoxide anion, which finally cleavages the porphine ring of In-TMPyP.
- 公益社団法人日本薬学会の論文
- 2002-12-01
著者
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Saito Yutaka
Department Of Pharmaceutical Sciences Graduate School Of Medicine And Dentistry And Pharmaceutical S
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Saito Y
Department Of Pharmaceutical Sciences Graduate School Of Medicine And Dentistry And Pharmaceutical S
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SAITO YUTAKA
Faculty of Pharmaceutical Sciences, Okayama University
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AKIZAWA Hiromichi
Graduate School of Pharmaceutical Sciences, Chiba University
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MIFUNE Masaki
Faculty of Pharmaceutical Sciences, Okayama University
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IWADO Akimasa
Faculty of Pharmaceutical Sciences, Okayama University
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MOTOHASHI Noriko
Kobe Pharmaceutical University
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AKIZAWA Hiromichi
Faculty of Pharmaceutical Sciences, Okayama University
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ASAHARA Hatsuki
The Graduate School of Natural Science and Technology, Okayama University
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HINOKIYAMA Toyohiro
Faculty of Pharmaceutical Sciences, Okayama University
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LIU Jian
The Graduate School of Natural Science and Technology, Okayama University
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Mifune Masaki
Department Of Pharmaceutical Sciences Graduate School Of Medicine And Dentistry And Pharmaceutical S
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Liu J
Yisheng Pharmaceutical Co. Ltd. Ji'an Chn
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Iwado Akimasa
Department Of Pharmaceutical Sciences Graduate School Of Medicine And Dentistry And Pharmaceutical S
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Mifune Masaki
Faculty Of Pharmaceutical Sciences Okayama University
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Arai H
The Graduate School Of Natural Science And Technology Okayama University
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Akizawa Hiromichi
Graduate School Of Pharmaceutical Sciences Chiba University
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Hazawa T
Faculty Of Pharmaceutical Sciences Okayama University
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Saito Yutaka
Faculty Of Engineering Kanazawa University
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Liu Jian
The Graduate School Of Natural Science And Technology Okayama University
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Saito Yutaka
Department of Pharmaceutical Sciences, Graduate School of Medicine and Dentistry and Pharmaceutical Sciences, Okayama University
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Mifune Masaki
Department of Pharmaceutical Sciences, Graduate School of Medicine and Dentistry and Pharmaceutical Sciences, Okayama University
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