Metal Isotope Effects on the Vibrational Spectra of Polymeric Metal Complexes. III. Infrared Spectra of [Bis (L-asparaginato) zinc (II)]_n

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概要

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• The infrared spectra of [bis (L-asparaginato) zinc (II)]_n and its isotopic complexes containing ^<64>Zn, ^<68>Zn and deuterium have been measured in the region between 4000 and 200 cm^<-1>. By referring to the isotope frequency shifts, three bands at 301,265 and 244 cm<-1> have been assigned to Zn-ligand stretching vibrations caused from coupling among Zn-O and Zn-N stretching vibrations. The frequency range of the Zn-O stretching vibrations suggests that the Zn-O binding force of zinc-amino acids is probably larger than has been considered.

• 公益社団法人日本薬学会の論文
• 1982-12-25

著者

• 斎藤 寛

  Faculty of Pharmaceutical Sciences, Okayama University

• 尾堂 順一

  Faculty of Pharmaceutical Sciences, Okayama University

• 田中 善正

  Faculty of Pharmaceutical Sciences, Okayama University

• 斎藤 寛

  Department Of Pharmaceutical Sciences Graduate School Of Medicine And Dentistry And Pharmaceutical S

• 斎藤 寛

  岡山大・薬

• 植松 真美

  Faculty of Pharmaceutical Sciences, Okayama University

• 田中 善正

  Faculty Of Pharmaceutical Sciences Okayama University:(present Address)department Of Biochemistry Co

• 植松 真美

  Faculty Of Pharmaceutical Sciences Okayama University

• 田中 善正

  Faculty Of Pharmaceutical Sciences Okayama University

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