Metal Isotope Effects on the Vibrational Spectra of Polymeric Metal Complexes. I. Infrared Spectra of [Bis (L-asparaginato) copper (II)]_n

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概要

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• The infrared spectra of [bis-(L-asparaginato) copper (II)] n and its isotopic complexes containing copper and hydrogen isotopes have been measured in the region between 4000 and 200 cm^<-1>. By referring to the isotope shifts on ^<63>Cu and ^<65>Cu substitution, two bands at 359 and 318 cm^<-1> have been assigned to metal-ligand stretching vibrations. The frequency shifts on N, N'-deuteration revealed that the Cu-N stretching frequency is larger than the Cu-O stretching frequency.

• 公益社団法人日本薬学会の論文
• 1981-04-25

著者

• 斎藤 寛

  Faculty of Pharmaceutical Sciences, Okayama University

• 尾堂 順一

  Faculty of Pharmaceutical Sciences, Okayama University

• 田中 善正

  Faculty of Pharmaceutical Sciences, Okayama University

• 斎藤 寛

  Department Of Pharmaceutical Sciences Graduate School Of Medicine And Dentistry And Pharmaceutical S

• 斎藤 寛

  岡山大・薬

• 田中 善正

  Faculty Of Pharmaceutical Sciences Okayama University:(present Address)department Of Biochemistry Co

• 田中 善正

  Faculty Of Pharmaceutical Sciences Okayama University

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