Metal Isotope Effects on the Vibrational Spectra of Polymeric Metal Complexes. IV. Infrared Spectra of trans-and cis-[Bis (D-alaninato) copper (II)]
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概要
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The infrared spectra of trans- and cis-[bis (D-alaninato) copper (II)]_n and their isotopic complexes containing ^<63>Cu, ^<65>Cu and deuterium were measured in the region between 4000 and 200 cm^<-1>. By referring to the isotope shifts on deuteration and ^<63>Cu and ^<65>Cu substitution, the bands around 370 and 320 cm^<-1> were assigned to the Cu-N and the Cu-O asymmetric stretching vibrations, respectively, for both the trans and cis complexes. The magnitudes of the copper isotope shifts are consistent with those calculated from the normal coordinate analysis by using a complete molecular conformation and an intermolecular force field. The trans-isomer showed three copper isotope sensitive bands, while the cis-isomer showed two.
- 公益社団法人日本薬学会の論文
- 1983-09-25
著者
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田中 善正
Faculty of Pharmaceutical Sciences, Okayama University
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斎藤 寛
Department Of Pharmaceutical Sciences Graduate School Of Medicine And Dentistry And Pharmaceutical S
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斎藤 寛
岡山大・薬
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町田 勝之輔
Faculty of Pharmaceutical Sciences, Kyoto University
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田中 善正
Faculty Of Pharmaceutical Sciences Okayama University:(present Address)department Of Biochemistry Co
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町田 勝之輔
Faculty Of Pharmaceutical Sciences Kyoto University
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田中 善正
Faculty Of Pharmaceutical Sciences Okayama University
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