Stereochemistry of Decahydroisoquinolines and Related Compounds. VII. Syntheses of trans-2-Methyl-1,2,3,4,4a, 5,6,7,8,8a-decahydro-7-isoquinolinols
スポンサーリンク
概要
- 論文の詳細を見る
The hitherto unknown stereoisomer of trans-2-methyl-1,2,3,4,4a, 5,6,7,8,8a-decahydro-7-isoquinolinol (XIIIc) and the known isomer of cis-2-methyl-1,2,3,4,4a, 5,6,7,8,8a-decahydro-7-isoquinolinol (XIIIa) were stereoselectively synthesized from 4-hydroxy-1,2,3,4,5,6-hexahydrohomophthalic acid 2,4-lactone (IX). The latter compound (IX) was separated from the reduction product of diethyl 4-hydroxyhomophthalate (II) whose configuration was already decided. Furthermore, another known isomer (XIIId) having trans ring juncture was prepared by different method from the known procedure.
- 公益社団法人日本薬学会の論文
- 1968-12-25
著者
-
藤原 靖弘
京都薬大
-
藤原 靖弘
Kyoto Pharmaceutical Univesity
-
岡本 正夫
Kyoto Pharmaceutical University
-
木本 正七郎
Kyoto College of Pharmacy
-
水本 隆章
Kyoto College of Pharmacy
関連論文
- 104(P-44) パプリカ(Capsicum annuum L.)の新規カロテノイドのMS/MSを用いた構造研究(ポスター発表の部)
- FAB CID-MS/MSによるカロテノイドの分析
- 91(P30) マガキCrassostrea gigasより得られた新規カロテノイドの構造(ポスター発表の部)
- 82(P07) トベラ種子の新規赤色カロテノイドtobiraxanthinの構造研究(ポスター発表の部)
- 日本産イチイ(Taxus cuspidata)果実のレトロタイプカロテノイドの構造と酸化作用
- P-18 トベラ種子の新規カロテノイドPittosporumxanthins B1,B2,C1,C2のMS/MS法を用いた構造研究(ポスター発表の部)
- Characteristics of a Lorentzian to Gaussian Transformation Function as a Weighting Function in Processing the Two-Dimensional Nuclear Magnetic Resonance Spectrum of a Drug-Phosphatidylcholine Vesicles Solution
- Variations in Average Electronic Excitation Energy as the Cause of ^C Nuclear Magnetic Resonance Protonation Shifts of 4-Aminoazobenzene
- 54(P17) シマシラキExcoecaria agallochaに含有されるジテルペンの構造(ポスター発表の部)
- マツグミTaxillus kaempferi及び宿主クロマツPinus thunbergiiの成分(第1報)マツグミのカテキン類とフラボン類について
- 1-II-9 Rhodobacter属光合成バクテリアの産生するカロテノイドとその抗酸化活性 : 第47回大会研究発表要旨
- 2,5-Dihydrofuryl-γ-lactam Derivatives from Hemerocallis fulva L. var. kwanso REGEL. II
- 52 トベラの新規C_カロテノイドPittosporumxanthin A1およびA2の構造研究(口頭発表の部)
- Studies on the Agalwood "Jinko." XII. Structures of Pentahydroxy-2-(2-phenylethy)chromone Derivatives
- Studies on the Agalwood (Jinko). XI. Structure of Dioxan-Linked Bi-phenylethylchromone Derivative
- Studies on Agalwood (Jinko). X. Structures of 2-(2-Phenylethyl)chromone Derivatives
- NOVEL 2,5-DIHYDROFURYL-γ-LACTAM DERIVATIVES FROM HEMEROCALLIS FULVA L. VAR. KWANZO REGEL
- Studies on Synthesis and Stereochemistry of 3-Methyloctahydroisocoumarins and 1-Methyloctahydro-3H-2-benzopyran-3-ones
- Studies on Synthesis of 10,11-Dihydro-5H-dibenzo[a, d]cycloheptene Derivatives. IV. : Photoreactions of 5-Substituted-5H-dibenzo[a, d]cycloheptenes with 1,2-Substituted Olefins and the Stereostructures of the Cycloaddition Products
- Studies on Synthesis of 10,11-Dihydro-5H-dibenzo[a, d]cycloheptene Derivatives, III. : Stereostructures of Isomeric 8,9-Dimethoxycarbonyldibenzo[2,3 : 5,6]bicyclo[5.2.0]nonan-4-ones Determined by ^1H-^1H and ^C-{^1H}Nuclear Overhauser Effects in Nucle
- Studies on the Agalwood (Jinko). VIII. : Structures of Bi-phenylethylchromone Derivatives
- Synthesis and Application of Imidazole Derivatives. Synthesis of 5-Methyl-7,8,9,10-tetrahydro-5H-azepino[1,2-α]benzimidazol-7-one and Related Compounds
- A Total Synthesis of Grifolin
- Synthesis and Application of Imidazole Derivatives : Preparation of Various Diketones from 1,n-Bis(1-methyl-1H-imidazol-2-yl)alkane-1,n-diones
- Synthesis and Application of Imidazole Derivatives. : Synthesis of (1-Methyl-1H-imidazol-2-yl)methanol Derivatives and Conversion into Carbonyl Compounds(Organic,Chemical)
- An Efficient Biogenetic-Type Transformation of 3-Tertiary-hydroxyalkanoic Acids to Olefinic Compounds(Organic,Chemical)
- Synthesis and Application of Imidazole Derivatives. Synthesis and Acyl Activation of 2-Acyl-1-methyl-1H-imidazoles(Organic,Chemical)
- 2-Amino-1,2,3,4-tetrahydroisoquinoline-1,3-dione並びにその誘導体の抗炎症, 鎮痛及び解熱作用
- tert-Butyl Carboxylatesの一改良合成法について
- 合成化学における1-Acylimidazoleの新しい利用
- 縮合Indole-4,7-dione関連化合物の合成研究(第3報)γ-Amino-n-butyric Acidおよびγ-Amino-β-hydroxy-n-butyric Acidを用いるPyrrole-2-acetic Acid誘導体の合成
- Use of β-Ketocarboxylic Acids for Syntheses of 6-Substituted 4-Hydroxy-2-pyrones and Acyclic β-Diketones
- 10,11-Dihydro-5H-dibenzo[a, d]cycloheptene誘導体の合成研究
- A Novel and Versatile Separation Method for Aldehydes
- Studies on the Syntheses of Condensed Indole-4,7-diones. II. Synthesis of Pyrrolo [1,2-a] indole-5,8-dione Derivatives
- 縮合Indole-4,7-dione関連化合物の合成研究(第1報)2,3-Dichloronaphthoquinoneを出発原料とするBenz[f]indole-4,9-dione誘導体の合成
- デカハイドロイソキノリン誘導体の立体化学(第12報) 2-Methyl-7-amino-cis-decahydroisoquinolineの合成
- Isocarbostyril関連化合物の合成研究(第7報) 2-MethylhomophthalimideとCH_2N_2の異常反応
- Isocarbostyril関連化合物の合成研究(第6報) 3-Alkoxyisocarbostyril誘導体の合成と反応
- Stereochemistry of 3-Methylhexahydrophthalide
- Isocarbostyril関連化合物の合成研究(第5報)2-Acylamido-3-aminoisocarbostyrilの閉環反応
- Studies on Peptides XVIII. Catalytic Hydrogenation of Methionine-containing Peptides
- The Use of Boron Trifluoride Etherate for Debenzyloxycarbonylation of Methionine-containing Peptides by Catalytic Hydrogenolysis
- Stereochemistry of Decahydroisoquinolines and Related Compounds. VIII. Syntheses of trans-4-Hydroxy-2-methyldecahydroisoquinolines
- THE STRUCTURES OF AH_ AND AH_, NEW BI- AND TRI-PHENYLETHYLCHROMONES FROM AGALWOOD(Communications to the Editor)
- Synthetic Studies on Lycoricidine and Related Compounds. II. Total Synthesis of (±)-Lycoricidine
- Synthetic Studies on Lycoricidine and Related Compounds. I. Synthesis of 4aH-r, 2H-cis, 2-Hydroxy-8,9-methylenedioxy-2,3,4,4a-tetrahydro-6 (5H)-phenanthridone
- デカハイドロイソキノリン誘導体の立体化学(第11報)
- Stereochemistry of 3-Methylhexahydrophthalide
- Stereochemistry of Decahydroisoquinolines and Related Compounds. X. Configurational Assignment of Epimeric 4-Hydroxy-2-methyl-cis-decahydroisoquinolines
- Stereochemistry of Decahydroisoquinolines and Related Compounds. VII. Syntheses of trans-2-Methyl-1,2,3,4,4a, 5,6,7,8,8a-decahydro-7-isoquinolinols
- Studies on Synthesis of 10,11-Dihydro-5H-dibenzo[a, d]cycloheptene Derivatives. II. : Synthesis and Structural Confirmation of Photocycloadducts, 8,9-Dimethoxycarbonyl-2 : 3,5 : 6-dibenzobicyclo[5.2.0] nonan-4-one and Related Compounds : Using Two-Dimensi
- Stereochemistry of Decahydroisoquinolines and Related Compounds. V. Syntheses of 2-Methyl-decahydro-8-isoquinolinols
- Stereochemistry of Decahydroisoquinolines and Related Compounds. III. Syntheses of cis-2-Methyl-decahydro-7-isoquinolinols.
- 合成化学における1-Acylimidazoleの新しい利用
- Studies on the Alkaloids of Amsonia elliptica ROEM ET SCHULT. IV. 17-Ketoyohimbine.
- On the Syntheses of 2-Methyl-7-decahydroisoquinolinols starting from Diethyl 4-Hydroxyhexahydrohomophthalate and Their Configurational Analysis on Their Structure