Studies on Structure of Griseolutein-B, a Streptomyces Antibiotic. III. The Complete Structure.
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概要
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A drastic reduction of diacetylgriseolutein-B monomethyl ester gave 1-methoxy-4,9-dimethylphenazine. Griseoluteic acid was assumed to be 1-methoxy-4-hydroxymethyl-9-carboxyphenazine. From these results and the periodate oxidation, griseolutein-B was concluded to be 1-methoxy-4-[(1,2-dihydroxyethoxy) methyl]-9-carboxyphenazine. The synthesis of 1-methoxy-4,6-dimethylphenazine and 1-methoxy-4,9-dimethylphenazine is described.
- 公益社団法人日本薬学会の論文
- 1958-10-15
著者
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中村 昭四郎
Institute Of Pharmaceutical Sciences
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中村 昭四郎
Institute Of Applied Microbiology University Of Tokyo
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