Asymmetric Total Syntheses of (+)-Coronafacic Acid and (+)-Coronatine
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概要
- 論文の詳細を見る
An asymmetric total synthesis of (+)-coronafacic acid, starting from (R)-(+)-4-acetoxy-2-cyclopen-1-one as a chiral source, was accomplished. Construction of the 1-hydrindanone framework was carried out by using intramolecular 1, 6-conjugate addition as the key step. Coupling between (+)-coronafacic acid and protected coronamic acid, and subsequent deprotection provided (+)-coronatine. This is the first asymmetric total synthesis of (+)-coronatine.
- 社団法人日本農芸化学会の論文
- 1997-04-23
著者
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Nara Shinji
Division Of Applied Bioscience Graduate School Of Agriculture Hokkaido University
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TOSHIMA Hiroaki
Department of Bioresource Science, College of Agriculture, Ibaraki University
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ICHIHARA Akitami
Department of Bioscience and Chemistry, Faculty of Agriculture, Hokkaido University
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NARA Shinji
Department of Bioscience and Chemistry, Hokkaido University
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Ichihara A
Hokkaido Univ. Sapporo Jpn
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Toshima H
Department Of Bioresource Science College Of Agriculture Ibaraki University
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Toshima Hiroaki
Department Of Applied Bioscience Graduate School Of Agriculture Hokkaido University
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Ichihara Akitami
Department Of Applied Bioscience Graduate School Of Agriculture Hokkaido University
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ICHIHARA Akitami
Department of Agricultural Chemistry, Faculty of Agriculture, Hokkaido University
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