Synthesis and Potato Cell Expansion-inducing Activity of the Stereochemically Restricted Bicyclic Analogue of 7-Epi-jasmonic Acid
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概要
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The stereochemically restricted bicyclic analogue of 7-epi-jasmonic acid was synthesized from a known bicyclo [3.3.0] octane derivative. The enol triflate derived from the bicyclic compound was subjected to palladium-catalyzed coupling with allyltributyltin to give the desired carbon skeleton. Selective catalytic hydrogenation and subsequent acidic hydrolysis gave a new bicyclic analogue of 7-epi-jasmonic acid. The ACC conjugate of the bicyclic analogue was also synthesized. This ACC conjugate exhibited only slightly weaker potato cell expansion-inducing activity than that of the JA standard.
- 社団法人日本農芸化学会の論文
- 2000-12-23
著者
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Nara Shinji
Division Of Applied Bioscience Graduate School Of Agriculture Hokkaido University
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ICHIHARA Akitami
Department of Bioscience and Chemistry, Faculty of Agriculture, Hokkaido University
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ICHIHARA Akitami
Division of Applied Bioscience, Graduate School of Agriculture, Hokkaido University
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TOSHIMA Hiroaki
Division of Applied Bioscience, Graduate School of Agriculture, Hokkaido University
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FUJINO Yumiko
Division of Applied Bioscience, Graduate School of Agriculture, Hokkaido University
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Fujino Y
Division Of Applied Bioscience Graduate School Of Agriculture Hokkaido University
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Fujino Yumiko
Division Of Applied Bioscience Graduate School Of Agriculture Hokkaido University
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Ichihara A
Hokkaido Univ. Sapporo Jpn
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Toshima H
Department Of Bioresource Science College Of Agriculture Ibaraki University
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Toshima Hiroaki
Division Of Applied Bioscience Graduate School Of Agriculture Hokkaido University
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