Polarization Dependence of Resonant X-Ray Emission Spectra in 3d^n Transition Metal Compounds with n=0, 1, 2, 3
スポンサーリンク
概要
- 論文の詳細を見る
The polarization dependence of 2p⟶3d⟶2p resonant X-ray emission spectroscopy (RXES) in 3d^1, 3d^2 and 3d^3 systems (TiF_3, VF_3 and Cr_2O_3, respectively) is measured and analyzed by means of the MX_6 (M denotes a transition metal and X denotes a ligand, respectively) cluster model. The results are compared with a previous one for the 3d^0 system (TiO_2). Generally, with increasing 3d electron number, the spectral structure of RXES becomes more complicated by the influence of the crystal field and the multiplet coupling effect. Moreover, we point out that the selection rules on the polarization dependence of RXES change with the 3d electron number and that a drastic resonance enhancement corresponding to the excitation to an antibonding state in the 3d^0 system is almost absent for the 3d^n systems with n=1, 2 and 3.
- 社団法人日本物理学会の論文
- 2002-01-15
著者
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魚住 孝幸
Institute For Solid State Physics The University Of Tokyo:riken
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SHIN Shik
Institute for Solid State Physics, University of Tokyo
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KOTANI Akio
Institute for Solid State Physics,University of Tokyo
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小谷 章雄
SPring-8
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小谷 章雄
理研 Spring-8:高エ研
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MATSUBARA Masahiko
Institute for Solid State Physics, University of Tokyo
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UOZUMI Takayuki
College of Engineering, Osaka Prefecture University
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Kotani Akio
Department Of Mechanical Engineering Osaka University
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HARADA Yoshihisa
The Institute of Physical and Chemical Research (RIKEN)
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小谷 章雄
理化学研究所播磨研究所
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Harada Yoshihisa
Riken
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Shin Shik
Institute For Solid State Physics (issp) University Of Tokyo
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Kotani Akio
Institute For Solid State Physics The University Of Tokyo
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Uozumi Takayuki
College Of Engineering Osaka Prefecture University
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Matsubara Masahiko
Institute For Solid State Physics The University Of Tokyo
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Kotani Akio
Institut De Physique Et Chimiedes Materiaux De Strasbourg Cnrs
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Matsubara Masahiko
Graduate School Of Science And Technology Kobe University
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KOTANI Akio
Department of Physics, Tohoku University : Institute for Solid State Physics, University of Tokyo
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