Electron Spin Resonance of Cu^<2+> Doped in TGS
スポンサーリンク
概要
- 論文の詳細を見る
The ESR spectra of Cu^<2+> doped in TGS were analyzed without any assumption in the symmetry of the crystal field. At room temperature, the directions of the maximum principal values of the A- and g- tensors agreed within 4°with the normal to the plane containing the two glycines, glycine 2 and glycine 3. the directions of g_x and g_y were nearly parallel to the bisector lines between N-N and O-O. At 77 K, two kinds of the absorption lines, the spectrum I and spectrum II, were observed. The former was decreased while the latter increased in intensity with increasing temperature. The parameters P, a_1^2 and κ in the ligand field were determined using the principal values of the g- and A-tensors. The p-values for the spectrum I and spectrum II were 0.036 cm^<-1> and 0.0776 cm^<-1>, respectively. This change of the p-value indicates that the electron cloud in Cu^<2+> ion contracts with the increase of rotation frequency of the protons in NH_3.
- 1973-12-05
著者
-
Kato Terumasa
Department Of Applied Physics Faculty Of Engineering Nagoya University
-
Abe Ryuji
Department Fo Applied Physics Faculty Of Engineering Nagoya University
関連論文
- Composite Glandular-Neuroendocrine Carcinoma of the Hilar Bile Duct : Report of a Case
- Granular Cell Tumors of the Breast : A Report of Two Cases
- ESR Study of SO^-_4 in LiKSO_4 at Low Temperatures
- The Relation between Complication Rate and Period between Aspiration and the Time of Diagnosis in Patients with Bronchial Foreign Bodies
- Dielectric Anomaly at the Phase Transition of RbD_3(SeO_3)_2
- Incommensurate Phase in γ-Irradiated RbH_3(SeO_3)_2 and RbD_3(SeO_3)_2
- ESR Line Shapes and Rotational Modes in the Structurally Incommensurate Phase of {N (CH_3)_4}_2CoCl_4 Crystal
- ESR Study of the Incommensurate-Commensurate Phase Transition in [N(CH_3)_4]_2ZnCl_4
- ESR Study of Cr^ Doped LiNH_4C_4H_4O_6・H_2O (LAT)
- ESR Study on Ferroelasticity of LAT
- ESR of Cu^-Doped NaNH_4-Tartrate (ARS)
- A Collision Tumor Composed of Adenocarcinoma and Malignant Lymphoma in the Remnant Stomach After Pancreatoduodenectomy : Report of a Case
- ESR Study of the Phase Transitions in {N (CH_3)_4}_2CoCl_4
- ESR Study of the Incommensurate-Commensurate Phase Transition in {N (CH_3)_4}_2CoCl_4
- ESR Line Shape in the Incommensurate Phase of K_2SeO_4 Crystal Doped with VO^ Ions
- Electron Spin Resonance of γ-Irradiated KH_2PO_4
- ESR Study of Fe^ Ions Doped in KDP Crystal
- Anomaly of ESR Line Width in γ-Irradiated KH_2PO_4 and KD_2PO_4
- ESR Study of NH^+_3 and SeO^-_3 Radicals in (NH_4)_2SO_4
- Potential Field Acting on the Hydrogens in LAT : LiNH_4C_4H_4O_6・H_2O
- On the Tunneling Motions of Proton and Deuteron in KDP and DKDP
- Electron Spin Resonance of Cu^ Doped in TGS
- Electron Spin Resonance of γ-Irradiated Triglycine Sulfate. I : Hindered Motion of CH^2 in a Free Radical CH^2COO^-
- Etching of Domains and Dislocations in Ferroelectric NaNO_2 Crystals
- A Microscopic Model for the Ferroelectric Phase Transition in (NH_4)_2SO_4
- Decay of Switching Current in Switching of BaTiO_3 Crystal due to a-Domain Formation
- Dielectric Relaxation of Na[K_(NH_4)_x]-Tartrate Crystals
- The Formation Mechanism of Domain Etch Patterns in Triglycine Sulfate Crystals
- Etch Pits of Dislocations in NaNO_2 Crystals
- Nonlinearity of the Dielectric Constant of Ferroelectric Triglycine Sulfate
- A New Evidence in the ESR Spectra of the Incommensurate Phase of Bis(p-Toluene Sulfonate) Ester of 2,4-Hexadiyne-1,6-Diol
- ESR Study of Tl^ Ion in LiTIC_4H_4O_6・H_2O and LiTl_(NH_4)C_4H_4O_6・H_2O
- ESR Study of RbH_3(SeO_3)_2 Crystals Doped with Cr^ Ions
- Effect of "Electronic Shielding" on the Dipole-Dipole Interaction in Rochelle Salt
- Coercive Fields of Rochelle Salt Heavily Irradiated with γ-Rays
- On the Puzzling Effect in NMR Spectrum of Lithium Sulfate Monohydrate
- Nuclear Magnetic Resonance in Rochelle Salt Determination of the Orientations of Proton Pairs
- ESR of γ-Irradiated DGN
- Anomalous Temperature Dependence of D Tensor in the ESR Spectrum of Fe^ Ions Doped in KDP and DKDP Crystals
- ESR Study of ADP-KDA Mixed Crystals
- Electron Spin Resonance of Gamma-Irradiated Rochelle Salt Single Crystal. II. : Analysis of Center No.1.
- Electron Spin Resonance of γ-Irradiated Triglycine Sulfate. II. : Internal Motion of Hydrogens and the Activation Energy in Glycine (I)
- ESR Study of NH_3^+ in Irradiated ADP 5% KDA
- Displacive Movement of the Radical in TGS near the Curie Point
- Optical Study on the Resultant Movement of Many Walls in Rochelle Salt
- Electron Spin Resonance of γ-Irradiated Triglycine Selenate
- Microscopic Origin of the Ferroelastic Phase Transition in LiNH_4C_4H_4O_6・H_2O
- ESR Study of NH^+_3 and SeO^-_3 Radicals in the Mixed Crystals [(NH_4)_R_x]_2SO_4(R=Rb, Cs)
- Anomalous Temperature Dependence of the ESR Lines of Cr^ Doped in TGS
- Dielectric Relaxation of Deuterated Rochelle Salt
- ESR Study on Polarization Mechanism in Radio-Electrets of FEP
- New Decoration Techniques for Revealing Antiparallel 180° Domains in BaTiO_3
- Dielectric and Piezoelectric Nonlinearity in KH_2PO_4
- Microwave Dielectric Nonlinearity of Ferroelectric Triglycine Sulfate
- Dielectric Constant and Conductivity of Very Thin SiO Films
- Antiferroelectricity Observed in the Mixed Crystal of LAT and LTT
- Effect of γ-Irradiation on the Dielectric Constants of KH_2PO_4
- Measurement of Microwave Dielectric Constant of Rochelle Salt by Means of Cavity Resonance with a New Device
- ESR Study of the Ferroelectric Phase Transition in CsH_2PO_4
- Gradual Increase of Coercive Field of X-Irradiated Rochelle Salt
- Phase Soliton Effect on ESR Line Shape in the Incommensurate Phase of K_2SeO_4 Crystal
- Nonlinear Dielectric Constants in Barium Titanate
- Dielectric Constant and Dielectric Relaxation Time of Rochelle Salt
- Electron Spin Resonance of Gamma-Irradiated Rochelle Salt Single Crystal : I. Analysis of Center No. 2
- ESR and ENDOR Investigations of the Ferroelectric BaMgF_4