Topographic Study on Staging Transition in H_2SO_4-Graphite Intercalation Compound by in situ Raman Scattering Measurements

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概要

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• The staging kinetics in H.50.-GIC's has been investigated experimentally by time-and space-dependent Raman scattering measurements. The stage transition fromstage n to n - 1 begins at the interface between the intercalant reservoir and the a-faceof the graphite crystal. The lower stage-(n - 1) domains emerge at the interface andproceed toward the inner region of the crystal. A narrow phase-boundary betweendifferent stage domains exists in the localized region and rnove toward the innerregion as the stage transformation progresses. The present results support the model[R. Nishitani, Y. Uno and H. Suematsu: Synth. Met. 7 (1983) 13] that the stagetransformation proceeds via propagation of the boundary between well-stagedregions. The origin of the stage disorder is also discussed.

• 社団法人日本物理学会の論文
• 1987-03-15

著者

• NISHINA Yuichiro

  The Research Institute for Iron,Steel and Other Metals,Tohoku University

• Nishina Yuichiro

  The Research Institute For Iron Steel And Other Metals

• Sasaki Yoshiro

  The Research Institute For Iron Steel And Other Metals Tohoku University

• Nishitani R

  Kyushu Inst. Technol. Fukuoka Jpn

• NISHITANI Ryusuke

  The Research Institute for Iron,Steel and Other Metals,Tohoku University

• Sasaki Y

  Osaka Univ. Osaka

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