Thermodynamic Metal-Insulator Transition in a Hydrogen-Bonded organic-Inorganic Hybrid Conductor,[Pd (H_<2-x>edag)(Hedag)]・TCNQ (x≈1/3)^<20)>
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概要
- 論文の詳細を見る
Heat cajcacity of a laydr'ogena-botaded orgaruic-itaorg?tnic hybrid couudtrctor,[Pd(H3 .edag)(Hedatg)]?TCNQ (r $ 173), ltas lceen precisely' rneastrred Icy adiabatic caloriutae-try loeloxv [00111 tetamperatttr'e. A x'ery 1.cro;rd lctrt definite aruonaaly NX'dS detected ar'otrnad 170 Katad attribtrted to 21 zaaetarl-itastrlator tr?trusition. The erutluatljoy atad etttrojoy of trattsition weredetermiraed and disctrssed ira relation to 21 possible order-disorder uneclaataistau of' prototas in thehydrogera bonds betxveen the Pd cozaaplexes and a possible Peierls rauechataisraa. The ataalysis shoxvsthe latter is taaore like13r. It is strggested that tlte lorag strperstrttcttrre ajopearittg below the tnet?xlitastrlator trsrnsition originates inu txxvo potetutial jceriodicities arisit?g f'rotm tlte not?-stoiclaiotaaetryx. Staradard theru'tuody?aataaic f'trractions are taTotrlated.
- 社団法人日本物理学会の論文
- 1999-11-15
著者
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齊藤 一弥
阪大理
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Mitani T
Japan Advanced Institute Of Science And Technology
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Mitani Tadaoki
Institute For Molecular Science
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Mitani T
The School Of Materials Science Japan Advanced Institute Of Science And Technology
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Mitani T
Japan Advanced Inst. Sci. And Technol. Ishikawa Jpn
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Saito K
Research Center For Molecular Thermodynamics Graduate School Of Science Osaka University
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Saito Kazuya
Microcalorimetry Research Center,Faculty of Science,Osaka University
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YAMAMURA Yasuhisa
Microcalorimetry Research Center,School of Science,Osaka University
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SORAI Michio
Microcalorimetry Research Center,School of Science,Osaka University
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MITANI Tadaoki
Japan Advanced Institute of Science and Technology
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Mitani Tadaoki
The School Of Materials Science Japan Advanced Institute Of Science And Technology
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KITAGAWA Hiroshi
Japan Advanced Institute of Science and Technology
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YOSHIDA Den
Japan Advanced Institute of Science and Technology
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Yamamura Yasuhisa
Research Center For Molecular Thermodynamics Graduate School Of Science Osaka University
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Saito G
Department Of Chemistry Faculty Of Science Tokyo Metropolitan University
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Sorai M
Osaka Univ. Osaka
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Kitagawa H
Univ. Hyogo Hyogo
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