Rearranged Vibsane-Type Diterpenes from Viburnum awabuki and Photochemical Reaction of Vibsanin B
スポンサーリンク
概要
- 論文の詳細を見る
Nine new diterpenes, neovibsanin D (1), 7-epi-neovibsanin D (2), 15-O-methylneovibsanin F (3), 14-epi-15-O-methylneovibsanin F (4), 15-O-methyl-18-oxoneovibsanin F (5), 2-O-methylneovibsanin H (6), 2-O-methylneovibsanin I (7), neovibsanin G (8), and 14-epi-neovibsanin G (9), were isolated from a methanol extract of the leaves of Viburnum awabuki. Their structures were elucidated to be uniquely rearranged vibsane-type diterpenes by spectroscopic analyses and comparison of NMR data with those of previously reported vibsane-type diterpenes. In addition, irradiation of vibsanin B (12) in methanol with a high-pressure Hg lump led to the direct formation of neovibsanins A (14) and B (15). These results gave a clue to understanding of the biogenetic interconversion of 11-membered vibsanins into neovibsanins.
- 社団法人日本薬学会の論文
- 2005-01-01
著者
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Morisaki M
Kyoritsu Coll. Pharmacy Tokyo Jpn
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福山 愛保
Faculty of Pharmaceutical Sciences, Tokushima Bunri University
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福山 愛保
徳島文理大薬
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MINAMI Hiroyuki
Institute of Pharmacognosy, Faculty of Pharmaceutical Sciences, Tokushima Bunri University
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FUKUYAMA Yoshiyasu
Institute of Pharmacognosy, Faculty of Pharmaceutical Sciences, Tokushima Bunri University
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児玉 三明
徳島文理大薬
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Minami H
Faculty Of Pharmaceutical Sciences Tokushima Bunri University
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Minami Hiroyuki
Institute Of Pharmacognosy Faculty Of Pharmaceutical Sciences Tokushima Bunri University
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KUBO Miwa
Institute of Pharmacognosy, Faculty of Pharmaceutical Sciences, Tokushima Bunri University
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YUASA Hiroaki
Institute of Pharmacognosy, Faculty of Pharmaceutical Sciences, Tokushima Bunri University
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MATSUO Asami
Institute of Pharmacognosy, Faculty of Pharmaceutical Sciences, Tokushima Bunri University
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FUJII Takako
Institute of Pharmacognosy, Faculty of Pharmaceutical Sciences, Tokushima Bunri University
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MORISAKI Mai
Institute of Pharmacognosy, Faculty of Pharmaceutical Sciences, Tokushima Bunri University
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HARADA Kenichi
Institute of Pharmacognosy, Faculty of Pharmaceutical Sciences, Tokushima Bunri University
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KUBO Miwa
Faculty of Pharmaceutical Sciences, Tokushima Bunri University
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Fujii Takako
Institute Of Pharmacognosy Faculty Of Pharmaceutical Sciences Tokushima Bunri University
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HARADA Kenichi
Faculty of Pharmaceutical Sciences, Tokushima Bunri University
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MORISAKI Masuo
Kyoritsu College of Pharmacy
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Fukuyama Yoshiyasu
Institute Of Pharmacognosy Faculty Of Pharmaceutical Sciences Tokushima Bunri University
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Morisaki Mai
Institute Of Pharmacognosy Faculty Of Pharmaceutical Sciences Tokushima Bunri University
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Minami H
Institute Of Pharmacognosy Faculty Of Pharmaceutical Sciences Tokushima Bunri University
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Matsuo Asami
Faculty Of Pharmaceutical Sciences Tokushima Bunri University
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Yuasa Hiroaki
Institute Of Pharmacognosy Faculty Of Pharmaceutical Sciences Tokushima Bunri University
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Harada Kenichi
Institute For Protein Research Osaka University:the Kitasato Institute
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