電解法およびハイブリッド電解法による内分泌撹乱物質の分解
スポンサーリンク
概要
- 論文の詳細を見る
Rate constants for decomposition reaction were measured for several phenols, i.e., bisphenol A, p-chlorophenol, p-octylphenol, 2,4-dichlorophenol, p-tert-butylphenol and for two other chemicals, benzophenone and PCB compounds in waste oil. The following methods were adopted: electrolysis, photolysis, sonolysis, photolytic electrolysis, and sonolytic electrolysis. The initial concentration was fixed at 50 mg/L except for the PCB, for which the concentration for all the isomers was 500 ng/L. The solvent was water, but for chemicals with insufficient solubility, mixtures with alcohols were used. Additional application of ultrasound led to remarkable enhancement for p-chlorophenol and 2,4-dichlorophenol. The electrolysis rate constant for PCB compounds was comparable to that for the phenols. Benzophenone was decomposed 10 times as slow as the phenols partly because of the solvent containing alcohols.
- 公益社団法人 電気化学会の論文
著者
-
HAYASHI Shigeo
Department of Applied Physics and Chemistry, University of Electro-Communications
-
Niwa Haruki
Department Of Applied Physics And Chemistry The University Of Electro-communications
-
Hatanaka Shin-ichi
Department Of Applied Physics And Chemistry The University Of Electro-communications
-
高上 直美
Department of Applied Physics and Chemistry, University of Electro-Communications
-
牧 昌次郎
Department of Applied Physics and Chemistry, University of Electro-Communications
-
Hayashi Shigeo
Department Of Applied Physecs And Chemistry University Of Electro-communications
-
大槻 和弘
Department Of Applied Physics And Chemistry University Of Electro-communications
-
MAKI Shojiro
Department of Applied Physics and Chemistry, University of Electro-Communications
-
TAKAGAMI Naomi
Department of Applied Physics and Chemistry, University of Electro-Communications
-
OHTSUKI Kazuhiro
Department of Applied Physics and Chemistry, University of Electro-Communications
-
NIWA Haruki
Department of Applied Physics and Chemistry, University of Electro-Communications
関連論文
- Effects of Aqueous Temperature on Sonolysis of Bisphenol A : Rate Constants Increasing with Temperature under Oxygen
- Synthesis, Chemi-and Bioluminescence Properties, and Photolysis of a Coelenterazine Analogue Having a Photoreactive Azido Group
- FAB CID-MS/MS of In-Source Fragment Ions as a Means to Differentiate Linkage Isomers of Branched Oligosaccharides : Le^a and Le^x Type Glycoconjugates
- Triboluminescence of 3, 6-Dibromocarbazole
- Pharmacological Characterization of the Newly Synthesized Nociceptin/Orphanin FQ-Receptor Agonist 1-[1-(1-Methylcyclooctyl)-4-piperidinyl]-2-[(3R)-3-piperidinyl]-1H-benzimidazole as an Anxiolytic Agent
- 有害物質分解における超音波利用 (特集/ソノケミストリーの新しい進展)
- Fundamental Studies on the Structures and Spectroscopic Properties of Imidazo[1, 2-α]pyrazin-3(7H)-one Derivatives
- Bioluminescence in the Limpet-Like Snail, Latia neritoides
- Characterization of [1-^C]-Specifically Labeled Amino Acids Using ESIMS/MS in the Selected Reaction Monitoring Mode
- Substituent Effects on the Solvatochromism of 2-Phenylimidazopyrazinones : Effective Control of the Color Variation Range and Sensitivity toward an Indication of the Proton-donor Ability of Solvents by an Electron-withdrawing Group Substitution
- Preparation of Deoxygenated Derivatives of Neoanisatin, a Neurotoxic Sesquiterpenoid Having a β-Lactone
- Differentiation between N-Acetylchondrosine and N-Acetyldermosine by Matrix-Assisted Laser Desorption Ionization Time of Flight Post Source Decay Mass Spectrometry
- FAB-CID Mass Spectrometry of Imidazolone Derivatives Related to the Chromophore of Aequorea Green Fluorescent Protein
- Substituent Effects on the Chemiluminescent Properties of Coelenterazine Analogues
- Plural Sonoluminescing Bubbles in Acoustic Fields of Higher Mode
- Simultaneous Observation of Motion and Size of a Sonoluminescing Bubble (Short Note)
- Effects of Sine Wave Modulation on Tracking of Resonance and Antiresonance of Piezoelectric Resonator
- 電解法およびハイブリッド電解法による内分泌撹乱物質の分解
- Measurements of Differential Cross Sections of Low-Energy Electrons Elastically Scattered by Gas Molecules.II.Scattering of 200-500 eV Electrons by Molecular Oxygen
- P-130 Chemistry on Oxygenation Site in Firefly Luciferase
- Acoustic emission from a sonoluminescing bubble
- Effect of Process Parameters on Ultrasonic Separation of Dispersed Particles in Liquid
- Rapid Tracking of Resonance and Antiresonance of a Piezoelectric Resonator
- Cubic ZnCdS Lattice-Matched to GaAs : A Novel Material for Short-Wavelength Optoelectronic Applications
- PB132 TOTAL SYNTHESIS OF OPTICALLY ACTIVE MONOCROTALINE, A CARCINOGENIC PYRROLIZIDINE ALKALOID
- PB77 SYNTHESIS OF (±)-PTAQUILOSIN, THE AGLYCON OF PTAQUILOSIDE, A CARCINOGENIC SUBSTANCE OF BRACKEN FERN
- A Quasi-Adiabatic Polarization Potential for Elastic Electron-Atom Scattering. : I. General Theory
- A Quasi-Adiabatic Polarization Potential for Elastic Electron-Atom Scattering. : II. Application to Hydrogen Atom
- Elastic Scattering of Electrons by Molecules at Intermediate Energies. : II. Application to Hydrogen Molecule
- Elastic Scattering of Electrons by Molecules at Intermediate Energies. : I. General Theory
- THERMAL CHANGE OF HYDROTALCITE-TYPE LAYERED DOUBLE HYDROXIDE Al_2Li(OH)_6[Fe(CN)_6]_・nH_2O UNDER OXIDIZING AND REDUCING ATMOSPHERES
- Influence of Electron-Donating and Electron-Withdrawing Substituents on the Chemiluminescence Behavior of Coelenterazine Analogs
- Sonoluminescence of Alkali-Metal Atoms in Sulfuric Acid: Comparison with That in Water
- Expression of Keratin 75 (K6hf) in Oral Squamous Cell Carcinoma
- Pharmacological Characterization of the Newly Synthesized Nociceptin/Orphanin FQ–Receptor Agonist 1-[1-(1-Methylcyclooctyl)-4-piperidinyl]-2-[(3R)-3-piperidinyl]-1H-benzimidazole as an Anxiolytic Agent
- Generalized Mean Relaxation Time Formalism for Activated Rate Processes without Manifest Detailed Balance
- Effects of External Modulation Signals on the Tracking of Resonance and Antiresonance of Piezoelectric Resonators
- A Glycerol Drop in Water Boosts Single-Bubble Sonoluminescence
- Determination of Elastic Stiffness and Piezoelectric e- and d-Constants of Piezoelectric Ceramic from Ultrasonic Velocity and Dielectric Constant
- Phase-Locked Loop Approach to the Automatic Measurement of Resonant and Anti-Resonant Frequencies of Piezoelectric Resonators : P: PIEZOELECTRICS
- Note on Shimizu-Saito's Tracking Methods : SAW and Communication Device
- Rapid Tracking of Resonance and Antiresonance of a Piezoelectric Reasonator : A phase-Locked Loop for Capacitive Loads : Ultrasonic Transduction
- ADSORPTION PROPERTIES OF MICROPOROUS SILICA PREPARED FROM METAKAOLINITE BY SELECTIVE LEACHING METHOD
- Double Scattering of Light by a Sonoluminescing Bubble and Many Small Particles
- Dehalogenation and Deamination of L-2-Amino-4-chloro-4-pentenoic Acid by Proteus mirabilis(Biological Chemistry)
- Isolation and identification of (2S)-2-amino-5-chloro-4-hydroxy-5-hexenoic acid from an Amanita of the section Roanokenses (Amanitaceae)
- Orientation of Fibers in Liquid by Ultrasonic Standing Waves
- A Waveform Reporduction Study of Time Domani Reflectomatry. : III. Inversion of Waveforms Reflected from a Diffuse Interface
- A Waveform Reproduction Study of Time Domain Reflectometry. I. : Reflections from a Diffuse Interface between Two Miscible Layers
- Practical guide of live imaging for developmental biologists
- A Waveform Reproduction Study of Time-Domain Reflectometry. II. : Quick Determination of Dielectric Relaxation Time
- Stochastic Model for Observation of Pulsed Signals on Digital Oscilloscope
- An Extension of the Kramers Rate Theory to Cusped and Smooth Potentials
- P7 CHARACTERIZATION OF SOME CLAY RAW MATERIALS IN NEPAL AND THEIR SINTERING BEHAVIOUR
- Photodissociation of Iodobenzene and Photoacoustic Detection of the Products Using a Dual-Purpose Q-switched YAG Laser
- Quantum Statistics of Multidimensional Nonlinear Oscillators : Condensed Matter and Statistical Physics
- Sonochemical Oxidation of Iodide Ions in Solution Undersaturated with Ambient Gases
- Effects of External Modulation Signals on the Tracking of Resonance and Antiresonance of Piezoelectric Resonators II. : Two Types of Sinusoidal Modulation
- Finite Angular Resolution Mie-Scattering Measurements of Sonoluminescing Bubbles
- Triboluminescence of 3,6-Dibromocarbazole
- Dynamics of Single Sonoluminecsing Bubble in Concentrated Aqueous Alkaline Halide Solutions
- 電解法およびハイブリッド電解法による内分泌撹乱物質の分解
- Dust Particles Counteract the Boosting of Single-Bubble Sonoluminescence by Glycerol Droplets
- Exponential Rule for Light-Scattering Sizing of Bubbles or Drops
- Double Scattering of Light by a Sonoluminescing Bubble and Many Small Particles
- Cellular Automata for Electrochemistry : A Practical Approach to the Understanding of Voltammograms
- Cellular Automata for Electrochemistry. Models of Fast Catalytic Reactions
- Stereoselective synthesis of (-)-trachelanthic acid and (+)-viridifloric acid, necic acid components of pyrrolizidine alkaloids from a common intermediate.
- Expression of myelin and lymphocyte protein (MAL) in oral carcinogenesis
- A Glycerol Drop in Water Boosts Single-Bubble Sonoluminescence
- Further Chemical Studies on Anisatin, a Neurotoxic Sesquiterpenoid Having a .BETA.-Lactone.
- Novel Transformation of Formyl Groups into Hydroxyl Groups Utilizing Deformylative Autoxidation of Aldehydes.
- Cellular Automata for Electrochemistry. Models of Fast Catalytic Reactions