Novel Transformation of Formyl Groups into Hydroxyl Groups Utilizing Deformylative Autoxidation of Aldehydes.
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概要
- 論文の詳細を見る
Structural requirements that cause deformylative autoxidation of aliphatic aldehydes are investigated. Decarbonylation of acyl radicals proceeds smoothly when the alkyl radicals that are formed can be stabilized by allylic conjugation. Further conjugation of the double bond in the allyl radical with a carbonyl or a cyclopropyl group allows position-selective peroxidation of the alkyl radical.
- 公益社団法人 日本化学会の論文
著者
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Kigoshi Hideo
Department Of Chemistry Faculty Of Science Nagoya University
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Niwa Haruki
Department Of Applied Physics And Chemistry The University Of Electro-communications
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Yamada Kiyoyuki
Department Of Chemistry Faculty Of Science Nagoya University
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Sawada Akihiko
Department Of Chemistry Faculty Of Science Nagoya University
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Imamura Yoshifumi
Department of Chemistry, Faculty of Science, Nagoya University
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