Limiting Current Density in Ionic Liquid Electrolyte for Lithium Batteries
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概要
- 論文の詳細を見る
The relationship between Li(I) transport property and the limiting current density was investigated in N-methyl-N-propylpyrrolidinium bis(trifluoromethylsulfonyl)amide (P13TFSA) at 30°C. The limiting current density in a LiTFSA/P13TFSA binary ionic liquid electrolyte was evaluated by chronoamperometry for a symmetric cell of Li|ionic liquid|Li, where the ionic liquid was incorporated in a porous polyethylene separator that was sandwiched between two Li electrodes. The diffusion process of Li(I) in the ionic liquid dominates the limiting current density in the cell. In addition to the Li(I) transport property of the electrolyte, the porosity and tortuosity of the separator has a significant effect on the limiting current density.
- 公益社団法人 電気化学会の論文
著者
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Dokko Kaoru
Department Of Applied Chemistry Graduate School Of Engineering Tohoku University
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Tachikawa Naoki
Department Of Chemistry And Biotechnology Yokohama National University
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Tamura Takashi
Department Of Applied Chemistry Faculty Of Science Science University Of Tokyo
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YOSHIDA Kazuki
Department of Applied Physics, Tohoku University
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Watanabe Masayoshi
Deparment of Pathology, Shiga University of Medical Science, School of Medicine
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PARK Jun-Woo
Department of Chemistry and Biotechnology, Yokohama National University
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TACHIKAWA Naoki
Department of Applied Chemistry, Faculty of Science and Technology, Keio University
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