EQCM Measurement of Sn(II)/Sn Reaction in 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide Room-temperature Ionic Liquid
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概要
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EQCM (Electrochemical Quartz Crystal Microbalance) measurement during Sn(II)/Sn electrode reaction in a room-temperature ionic liquid was conducted using an impedance method EQCM, which can measure the resonance resistance and frequency simultaneously. The mass increased during Sn deposition and decreased during Sn dissolution. The viscosity and density of the electrolyte near the electrode, ηLρL, can be estimated by monitoring the resonance resistance. The change of the ηLρL value during Sn(II)/Sn electrode reaction could be accounted for by the concentration profile of Sn(II) near the electrode.
- 公益社団法人 電気化学会の論文
著者
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Katayama Yasushi
Department Of Applied Chemistry Faculty Of Science And Technology Keio University
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Miura Takashi
Department Of Anatomy And Developmental Biology Graduate School Of Medicine Kyoto University
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TACHIKAWA Naoki
Department of Applied Chemistry, Faculty of Science and Technology, Keio University
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SERIZAWA Nobuyuki
Department of Applied Chemistry, Faculty of Science and Technology, Keio University
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