Thermoelectromotive Force of Some Redox Couples in an Amide-type Room-temperature Ionic Liquid
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概要
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Reaction entropies of some metal complex redox couples in an amide-type room-temperature ionic liquid, 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide (BMPTFSA) have been estimated by measuring the thermoelectromotive force at a non-isothermal cell. It is suggested that the reaction entropy is dependent on the difference in the charge densities of the oxidant and reductant of a redox couple, probably related to the coulombic interaction between the redox species and the ions composing the ionic liquid.
- 公益社団法人 電気化学会の論文
著者
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Katayama Yasushi
Department Of Applied Chemistry Faculty Of Science And Technology Keio University
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Tachikawa Naoki
Department Of Chemistry And Biotechnology Yokohama National University
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Miura Takashi
Department Of Anatomy And Developmental Biology Graduate School Of Medicine Kyoto University
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MIGITA Tsubasa
Department of Applied Chemistry, Faculty of Science and Technology, Keio University
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TACHIKAWA Naoki
Department of Applied Chemistry, Faculty of Science and Technology, Keio University
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