Crystal and molecular structures of octaethylporphinium(monocation) triiodide and its benzene hemisolvate.

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概要

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• The structure of the triclinic form of octaethylporphinium (monocation) triiodide was determined by X-ray analysis. The structure of the previously determined orthorhombic form was refined using diffractometer data. The final R values for the triclinic and the orthorhombic forms were 0.060 and 0.069, respectively. The present analysis has established the inherent structure of porphyrin monocations; three pyrrole rings are coplanar and the plane of the fourth ring is tilted from the mean plane of the other three. The magnitude of the tilt angle is 12.5° for the triclinic form and 16.1° for the orthorhombic form.

• 公益社団法人 日本化学会の論文

著者

• Watanabe Ei-ichi

  Departments Of Circulation Research Institute Of Environmental Medicine Nagoya University

• Yoshida Zen-ichi

  Department Of Applied Chemistry Faculty Of Science And Engineering Kinki University

• SASADA Yoshio

  Laboratory of Chemistry for Natural Products, Tokyo Institute of Technology

• OGOSHI Hisanobu

  Department of Chemistry, Faculty of Engineering, Technical University of Nagaoka

• Takenaka Akio

  Laboratory of Chemistry for Natural Products, Tokyo Institute of Technology

• Ogoshi Hisanobu

  Department of Synthetic Chemistry, Kyoto University

• Hirayama Noriaki

  Laboratory of Chemistry for Natural Products, Tokyo Institute of Technology

• Sasada Yoshio

  Laboratory of Chemistry for Natural Products, Faculty of Science, Tokyo Institute of Technology

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