Sulfur-carbonyl interaction in rigid .BETA.-keto sulfides.
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概要
- 論文の詳細を見る
The electron donating ability of sulfur to a positively charged center through space was examined by means of ultraviolet spectroscopy. 7-Thiabicyclo[2.2.1]heptan-2-one and -2,5-dione exhibited finely separated charge transfer band (from divalent sulfide to carbonyl) at 260 nm in UV spectra, the longest wave-length for S–Cco charge transfer band so far reported. The assignment of these CT bands was confirmed by comparison with relevant reference compounds.
- 公益社団法人 日本化学会の論文
著者
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Tamaru Yoshinao
Department Of Applied Chemistry Faculty Of Engineering Nagasaki University
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Yoshida Zen-ichi
Department Of Applied Chemistry Faculty Of Science And Engineering Kinki University
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Tabushi Iwao
Department oe Pharmaceutical Sciences, Kyashu University
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