Vibrational Spectrum of Trisdimethylaminocyclopropenium Perchlorate
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概要
- 論文の詳細を見る
Infrared spectrum in the region 4000–100 cm<SUP>−1</SUP> and Raman spectrum of trisdimethylaminocyclopropenium perchlorate (1) have been measured. Band assignments have been made on the basis of normal coordinate analysis and deuteration of the methyl groups. Remarkable stabilization of cyclopropenium ion due to the peripheral amino groups is attributed to a marked delocalization of the positive charge of the ring on the amino groups through conjugation. Peculiar electronic structure of trisaminocyclopropenium ion is explained in terms of its vibrational spectrum.
- 公益社団法人 日本化学会の論文
著者
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Yoshida Zen-ichi
Department Of Applied Chemistry Faculty Of Science And Engineering Kinki University
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OGOSHI Hisanobu
Department of Chemistry, Faculty of Engineering, Technical University of Nagaoka
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Ogoshi Hisanobu
Department of Synthetic Chemistry, Kyoto University
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Tawara Yoshiyuki
Department of Synthetic Chemistry, Kyoto University
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Hirota Shizue
Department of Synthetic Chemistry, Kyoto University
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