The structure of liquid water by neutron scattering. II. Temperature dependence of the liquid structure.
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概要
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The structure factors for heavy water at 25, 50, 70, and 95 °C were determined in the range of <I>Q</I>, 1.4–20 Å<SUP>−1</SUP>, by means of the time-of-flight (TOF) neutron diffraction method using the electron linear accelerator (LINAC). An analysis of the neutron diffraction data was made by applying a new general theoretical procedure of analysis for the fluid system composed of molecular clusters with various sizes. Structure factors were calculated according to the general procedure for the pentamer-monomer mixture model as a mixture of regular tetrahedral pentamers and non-bonded monomers with a due assignment of pentamer fraction at each temperature. Excellent agreement was obtained between the calculated and observed structure factors at temperatures in 25–95 °C. Combined with the preceding result (N. Ohtomo, K. Tokiwano, and K. Arakawa, <I>Bull. Chem. Soc. Jpn.</I>, <B>54</B>, 1802 (1981)), it was concluded that the pentamer-monomer mixture model is the best one for water from room temperature to near the boiling point.
- 公益社団法人 日本化学会の論文
著者
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Ohtomo Norio
Faculty Of Engineering Hokkaido University
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Tokiwano Kazuo
Faculty Of Engineering Hokkaido University
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Arakawa Kiyoshi
Research Institute Of Applied Electricity Hokkaido University
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