Ultrasonic and Thermodynamic Study on Solute-Solvent Interaction. Binary Mixtures of 1,2-Dichloroethane with Benzene, Toluene, <I>p</I>-Xylene and Cyclohexane
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概要
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The sound velocity and density of binary mixtures of benzene, toluene, <I>p</I>-xylene and cyclohexane with 1,2-dichloroethane (DCE) as a common component were measured at temperature 20–40°C, and the excess molar volume and excess compressibility of these systems were calculated. They were found to be positive. The excess compressibility is independent of temperature in the DCE-benzene system. Thermodynamical properties and the nature of intermolecular interaction in the systems were discussed. It has been shown that there is a certain weak attraction between DCE and aromatic molecules, and that there is no complex formation <I>viz.</I>, hydrogenbonding or change transfer complex. It has been proposed that the interaction between <I>gauche</I> form of DCE and aromatic molecules is of electrostatic nature (dipole-induced dipole or hyperpolarizability).
- 公益社団法人 日本化学会の論文
著者
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Arakawa Kiyoshi
Research Institute Of Applied Electricity Hokkaido University
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Arakawa Kiyoshi
Research Institute of Applied Electricity, Hokkaido University
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Kiyohara Osamu
Research Institute of Applied Electricity, Hokkaido University
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