Ultrasonic and Thermodynamic Study on Solute-Solvent Interaction. Binary Mixtures of <I>t</I>-Butyl Chloride, <I>t</I>-Butyl Bromide and 1,1,1-Trichloroethane with Carbon Tetrachloride, Benzene and <I>p</I>-Xylene
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概要
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Sound velocity and density of binary mixtures of <I>t</I>-butyl chloride (<I>t</I>BC), <I>t</I>-butyl bromide (<I>t</I>BB), and 1,1,1-trichloroethane (TCE) with carbon tetrachloride (CT), benzene (B), and <I>p</I>-xylene (<I>p</I>X) were measured at temperatures, 25 and 35°C. The excess molar volume and excess compressibility of these systems were calculated. The temperature dependency of excess volume was negative for aromatic solutions and positive for CT solutions. The temperature coefficients of excess compressibility were negative for all systems. The relation between thermodynamic properties and intermolecular interactions in these systems were discussed. Two systems, B-TCE and CT-TCE, were found to be nearly ideal. The solute-solvent interactions in CT-<I>t</I>BC and <I>t</I>BC-TCE systems were found to be more attractive than in other systems.
- 公益社団法人 日本化学会の論文
著者
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Arakawa Kiyoshi
Research Institute Of Applied Electricity Hokkaido University
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Kiyohara Osamu
Research Institute of Applied Electricity, Hokkaido University
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