An ultrasonic method for determination of the difference in hard-sphere volume of conformational isomers.
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概要
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An ultrasonic method for determining the difference in hard-sphere volume of conformational isomers from sound velocity has been worked out, its accuracy being improved by taking the temperature dependence of the effective hard-sphere diameter into account. The difference for 1,2-dibromoethane, 1,1,2-trichloroethane, methylcyclohexane, and 1,2-dichloroethane was determined. The fractions of volume differences <I>ΔV</I>⁄<I>V</I> in these liquids were found to be 4.<SUB>5</SUB>, 5, 11, and 19% for 1,2-dibromo-, 1,1,2-trichloroethane, methylcyclohexane, and 1,2-dichloroethane, respectively.
- 公益社団法人 日本化学会の論文
著者
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Arakawa Kiyoshi
Research Institute Of Applied Electricity Hokkaido University
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Aoi Masakatsu
Research Institute of Applied Electricity, Hokkaido University
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